Abstract
Recent progress in the catalytic hydrosilylation of organic compounds containing carbon-carbon multiple bonds is reviewed. Hydrosilylation of carbon-carbon multiple bonds catalyzed with transition metal complexes remains the most commercially utilized process for formation of organosilicon compounds. During the last two decades, a number of simple and versatile catalytic systems including homogenous and heterogenous systems and even those for asymmetric catalysis procedures have been developed. These transition metal catalysts increased catalytic efficiency as well as regioselectivity and stereoselectivity.
Keywords: Hydrosilylation, catalysis, carbon-carbon multiple bonds, transition metal complexes, Silicon, phosphonic acids, bisphosphonic acids, organosilicon-mediated synthesis, phosphites, regioselective hydrosilylation, Palladium Complexes, chiral phosphines, asymmemetric hydrosilylation, Nickel Complexes, Cobalt Complexes
Current Organic Chemistry
Title: Recent Progress in Transition Metal Complexes Catalyzed Hydrosilylation of Carbon-Carbon Multiple Bonds
Volume: 15 Issue: 16
Author(s): Jiajian Peng, Ying Bai, Jiayun Li and Guoqiao La
Affiliation:
Keywords: Hydrosilylation, catalysis, carbon-carbon multiple bonds, transition metal complexes, Silicon, phosphonic acids, bisphosphonic acids, organosilicon-mediated synthesis, phosphites, regioselective hydrosilylation, Palladium Complexes, chiral phosphines, asymmemetric hydrosilylation, Nickel Complexes, Cobalt Complexes
Abstract: Recent progress in the catalytic hydrosilylation of organic compounds containing carbon-carbon multiple bonds is reviewed. Hydrosilylation of carbon-carbon multiple bonds catalyzed with transition metal complexes remains the most commercially utilized process for formation of organosilicon compounds. During the last two decades, a number of simple and versatile catalytic systems including homogenous and heterogenous systems and even those for asymmetric catalysis procedures have been developed. These transition metal catalysts increased catalytic efficiency as well as regioselectivity and stereoselectivity.
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Cite this article as:
Peng Jiajian, Bai Ying, Li Jiayun and La Guoqiao, Recent Progress in Transition Metal Complexes Catalyzed Hydrosilylation of Carbon-Carbon Multiple Bonds, Current Organic Chemistry 2011; 15 (16) . https://dx.doi.org/10.2174/138527211796378415
DOI https://dx.doi.org/10.2174/138527211796378415 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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