Abstract
This review highlights the advances in molecular recognition based on the linear molecular receptors in the past decade. Three kinds of linear receptors that bind discrete neutral, cationic and anionic organic molecules, metal ions, and halide anions are described. The first are foldamer receptors that are induced by intramolecular non-covalent forces to spontaneously fold into compact conformations. The second are linear molecules that themselves are structurally flexible but turn into folded conformations upon binding. The third are functionalized foldamers that consist of hydrogen bonding-driven preorganized arylamide-based linkers and attached binding sites fullerene units.
Keywords: Molecular recognition, supramolecular chemistry, foldamer, linear receptor, non-covalent interaction, m-Phenyleneethynylene (mPE) Foldamers, DMAP, groove binding, ICD signals, α- and β-D-glucoses, Ethynylindolyl Oligomer Foldamers, Oligopyridine-dicarboxamide strands, Pyridine-Naphthyridine Oligomers, Triazole-Benzene Oligomers, OLIGOCHOLATE
Current Organic Chemistry
Title: Molecular Recognition with Linear Molecules as Receptors
Volume: 15 Issue: 9
Author(s): Yuan-Yuan Zhu, Gui-Tao Wang and Zhan-Ting Li
Affiliation:
Keywords: Molecular recognition, supramolecular chemistry, foldamer, linear receptor, non-covalent interaction, m-Phenyleneethynylene (mPE) Foldamers, DMAP, groove binding, ICD signals, α- and β-D-glucoses, Ethynylindolyl Oligomer Foldamers, Oligopyridine-dicarboxamide strands, Pyridine-Naphthyridine Oligomers, Triazole-Benzene Oligomers, OLIGOCHOLATE
Abstract: This review highlights the advances in molecular recognition based on the linear molecular receptors in the past decade. Three kinds of linear receptors that bind discrete neutral, cationic and anionic organic molecules, metal ions, and halide anions are described. The first are foldamer receptors that are induced by intramolecular non-covalent forces to spontaneously fold into compact conformations. The second are linear molecules that themselves are structurally flexible but turn into folded conformations upon binding. The third are functionalized foldamers that consist of hydrogen bonding-driven preorganized arylamide-based linkers and attached binding sites fullerene units.
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Cite this article as:
Zhu Yuan-Yuan, Wang Gui-Tao and Li Zhan-Ting, Molecular Recognition with Linear Molecules as Receptors, Current Organic Chemistry 2011; 15 (9) . https://dx.doi.org/10.2174/138527211795378218
DOI https://dx.doi.org/10.2174/138527211795378218 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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