Abstract
A review of synthetic methodologies reported in the last five years that yield N-heterocyclic products by intramolecular cyclization of organic azides with a particular emphasis on transformations catalyzed by metal complexes is presented. These reactions have been classified according to the ring size of the formed heterocycle.
Keywords: Amination reactions, Heterocycles, Homogeneous catalysis, Intramolecular cyclisations, Organic azides, Transition metal complexes, Dihydropyrroles, Benzimidazoles, isoquinolones, benzo[c]phenanthridine alkaloids, p-tolyl-sulfonyl
Current Organic Chemistry
Title: Synthesis of Heterocycles by Intramolecular Cyclization of Organic Azides
Volume: 15 Issue: 10
Author(s): Sergio Cenini, Fabio Ragaini, Emma Gallo and Alessandro Caselli
Affiliation:
Keywords: Amination reactions, Heterocycles, Homogeneous catalysis, Intramolecular cyclisations, Organic azides, Transition metal complexes, Dihydropyrroles, Benzimidazoles, isoquinolones, benzo[c]phenanthridine alkaloids, p-tolyl-sulfonyl
Abstract: A review of synthetic methodologies reported in the last five years that yield N-heterocyclic products by intramolecular cyclization of organic azides with a particular emphasis on transformations catalyzed by metal complexes is presented. These reactions have been classified according to the ring size of the formed heterocycle.
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Cite this article as:
Cenini Sergio, Ragaini Fabio, Gallo Emma and Caselli Alessandro, Synthesis of Heterocycles by Intramolecular Cyclization of Organic Azides, Current Organic Chemistry 2011; 15 (10) . https://dx.doi.org/10.2174/138527211795378164
DOI https://dx.doi.org/10.2174/138527211795378164 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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