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Current Organic Chemistry


ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

Progress in Intermolecular Carbon Radical Addition to Imine Derivatives

Author(s): Hideto Miyabe, Eito Yoshioka and Shigeru Kohtani

Volume 14, Issue 12, 2010

Page: [1254 - 1264] Pages: 11

DOI: 10.2174/138527210791330477

Price: $65


The intermolecular radical addition to the carbon atom of imine derivatives has received much less attention until recently, although the use of radical reaction in organic synthesis has continued to increase. This review highlights the intermolecular carbon-carbon bond forming reactions based on carbon radical addition to the carbon-nitrogen double bond. Particularly, the radical reactions of oxime ethers, hydrazones, sulfonylimines, ketimines, and so on are summarized. In this review, strategies for diastereo- and enantioselective radical reactions of imine derivatives are also summarized.

Keywords: Radical, imine, oxime ether, hydrazone, sulfonylimine, amine, diastereoselective, enantioselective

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