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Current Organic Chemistry


ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

Acid- and Base-Promoted Rearrangements of Cycloalkane-Fused Heterocycles

Author(s): Ferenc Csende, Ferenc Miklos and Andrea Porkolab

Volume 14, Issue 8, 2010

Page: [745 - 753] Pages: 9

DOI: 10.2174/138527210791111867

Price: $65


Certain cycloalkane-anellated heterocycles undergo rearrangement under basic or acidic conditions via ring-contraction, ringexpansion or ring-opening pathways to afford new or unusual compounds. The reactivities and properties of cycloalkane-fused heterocycles differ significantly from those of heteroaromatic ring systems. Possible mechanisms are also discussed.

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