Abstract
N-heterocyclic carbenes (NHCs) found numerous applications as ligands for transition metal complexes during the last two decades. Only recently, however, increasing attention is turning to high oxidation state organometallics with NHC ligands. A surprising number of stable complexes of that type have been described mainly during the last five years and several of them have potential for application in both homogeneous and heterogeneous catalysis of organic reactions. This article describes the preparation and characteristics of these high oxidation state organometallic complexes with NHC ligands and gives an outlook on their possible applications.
Keywords: N-heterocyclic carbenes (NHCs), NHC ligands, transition metal complexes, organometallics, heterogeneous catalysis, oxidation state
Current Organic Chemistry
Title: High Oxidation State Transition Metal Complexes Ligated with N-Heterocyclic Carbenes
Volume: 12 Issue: 17
Author(s): K. R. Jain, W. A. Herrmann and F. E. Kuhn
Affiliation:
Keywords: N-heterocyclic carbenes (NHCs), NHC ligands, transition metal complexes, organometallics, heterogeneous catalysis, oxidation state
Abstract: N-heterocyclic carbenes (NHCs) found numerous applications as ligands for transition metal complexes during the last two decades. Only recently, however, increasing attention is turning to high oxidation state organometallics with NHC ligands. A surprising number of stable complexes of that type have been described mainly during the last five years and several of them have potential for application in both homogeneous and heterogeneous catalysis of organic reactions. This article describes the preparation and characteristics of these high oxidation state organometallic complexes with NHC ligands and gives an outlook on their possible applications.
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Cite this article as:
Jain R. K., Herrmann A. W. and Kuhn E. F., High Oxidation State Transition Metal Complexes Ligated with N-Heterocyclic Carbenes, Current Organic Chemistry 2008; 12 (17) . https://dx.doi.org/10.2174/138527208786241466
DOI https://dx.doi.org/10.2174/138527208786241466 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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