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Current Organic Chemistry


ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

Review Article

New Trends in the Development of C-P Bond Forming Reactions

Author(s): Vadim D. Romanenko*

Volume 25, Issue 17, 2021

Published on: 10 June, 2021

Page: [1937 - 1976] Pages: 40

DOI: 10.2174/1385272825666210610153954

Price: $65


This account reviews some innovative (“non-classical”) synthetic strategies for the formation of CP bonds developed during the last decades. It provides examples of the most important milestones in this field, highlighting the state-of-art of functional phosphoruscontaining molecules. Among these are the direct functionalization of organic substrates through chlorine-free reactions with elemental phosphorus, syntheses based on phosphinidene (RP) transfer, phosphorylating methodology employing multiple bonds containing P(III) compounds, reactions with stable heterocyclic carbenes, and synthetic approaches using phosphaethynolate and bis(trichlorosilyl)phosphide salts.

Keywords: C-P bond forming reactions, elemental phosphorus, phosphinidene transfer, phospha-Wittig reaction, phospha-Fritsch- Buttenberg-Wiechell rearrangement, phosphaalkynes, phosphaalkenes, phosphinylidene carbenoids, phosphaethynolate anion, bis(trichlorosilyl) phosphide salts.

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