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Current Organic Chemistry


ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

Review Article

Recent Progress in Arylation Reactions with Diaryliodonium Salts

Author(s): Dan Wang, Qian Li, Mengting Li, Zhengyin Du* and Ying Fu*

Volume 25, Issue 11, 2021

Published on: 25 May, 2021

Page: [1298 - 1320] Pages: 23

DOI: 10.2174/1385272825666210512015410

Price: $65


In recent years, diaryliodonium salts have been extensively exploited as green, efficient electrophilic arylation reagents in a large range of organic synthesis. These arylating reagents exhibit relatively high reactivity and good selectivity in many transformations. In this review, the synthetic methods towards diaryliodonium salts are described briefly, and the research progress in arylation reactions by using diaryliodoniums in C-C and carbonheteroatom bond formation, especially in enantioselective C-C bond formation and cascade reactions, in recent ten years is summarized and discussed in detail.

Keywords: Diaryliodonium salts, arylation reaction, nucleophiles, heterocycles, cyclization reaction, cyclic diaryliodonium salt.

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