Login Register Cart 0
Generic placeholder image

Letters in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

Back
Journal Home About Journal Editorial Board Journal Insight Current Issue Volumes/Issues
Subscribe
Research Article

Simple Way for Ag-NPs Preparation based on Starch Macromolecule

Author(s): H.M. Fahmy, A.A. Aly and A. Abou-Okeil*

Volume 19, Issue 5, 2022

Published on: 02 February, 2021

Page: [400 - 407] Pages: 8

DOI: 10.2174/1570178618666210202154635

Price: $65

Abstract

Finding a sustainable, inexpensive way for Ag-NPs synthesis is considered as one of the most important requirements for industrial application. Oxidized starch was prepared using sodium periodate. Oxidized starch (DAS) was characterized by measuring aldehyde content and using FTIR spectroscopy. DAS was used as a reducing and stabilizing agent for the preparation of Ag nanoparticles (Ag-NPs). Factors that may affect the preparation of Ag-NPs including pH, AgNO3/DAS molar ratio, temperature and time, were studied. UV-Vis. spectroscopy and particle size analysis showed that DAS could act as a reducing and stabilizing agent for the preparation of Ag-NPs and the mean particle size was 19 nm. The so prepared Ag-NPs were used as antibacterial agent for cotton fabric using the pad dry cure method. The results of the antibacterial test showed that the presence of Ag-NPs enhanced the antibacterial properties of the treated cotton fabrics.

Keywords: Starch, hydrolyzed starch, oxidation, Ag-nanoparticles, Antibacterial, cotton fabric.

« Previous Next »
Graphical Abstract

[1]
Chung, D.S.; Kim, H.; Ko, J.; Lee, J.; Hwang, B.; Chang, S. J. Chem., 2018, 12, 1-10.
[2]
Venkatesham, M.; Ayodhya, D.; Madhusudhan, A.; Babu, N.V.; Veerabhadram, G. Appl. Nanosci., 2014, 4, 113-119.
[http://dx.doi.org/10.1007/s13204-012-0180-y]
[3]
Yun, S.; Hagfeldt, A.; Ma, T. ChemCatChem, 2014, 6, 1584-1588.
[http://dx.doi.org/10.1002/cctc.201402003]
[4]
Yun, S.; Wang, L.; Zhao, C.; Wang, Y.; Ma, T. Phys. Chem. Chem. Phys., 2013, 15(12), 4286-4290.
[http://dx.doi.org/10.1039/c3cp44048f ] [PMID: 23420305]
[5]
Abou-Okeil, A.; Sheta, A.M.; Amr, A.; Ali, M.A. Carbohydr. Polym., 2012, 90(1), 658-666.
[http://dx.doi.org/10.1016/j.carbpol.2012.05.093 ] [PMID: 24751090]
[6]
Ortega‐Arroyo, L.; Martin‐Martinez, E.S.; Aguilar‐Mendez, M.A.; Cruz‐Orea, A.; Hernandez‐Pérez, I.; Glorieux, C. Starke, 2013, 65, 814-821.
[http://dx.doi.org/10.1002/star.201200255]
[7]
Fahmy, H.M.; Eid, R.A.; Hashem, S.S.; Amr, A. Carbohydr. Polym., 2013, 92(2), 1539-1545.
[http://dx.doi.org/10.1016/j.carbpol.2012.11.008 ] [PMID: 23399186]
[8]
Ibrahim, N.A.; Amr, A.; Eid, B.M.; Mohamed, Z.E.; Fahmy, H.M. Carbohydr. Polym., 2012, 89(2), 648-660.
[http://dx.doi.org/10.1016/j.carbpol.2012.03.068 ] [PMID: 24750770]
[9]
Fahmy, H.; Aly, A.; Mohamed, Z. Int. J. Chemtech Res., 2016, 9, 96-109.
[10]
Tan, Y.; Wang, Y.; Jiang, L.; Zhu, D. J. Colloid Interface Sci., 2002, 249(2), 336-345.
[http://dx.doi.org/10.1006/jcis.2001.8166 ] [PMID: 16290606]
[11]
Mallick, K.; Witcomb, M.J.; Scurrell, M.S. Mater. Chem. Phys., 2005, 90, 221-224.
[http://dx.doi.org/10.1016/j.matchemphys.2004.10.030]
[12]
Mohanpuria, P.; Rana, N.K.; Yadav, S.K. J. Nanopart. Res., 2008, 10, 507-517.
[http://dx.doi.org/10.1007/s11051-007-9275-x]
[13]
Soliman, Y. Radiat. Phys. Chem., 2014, 102, 60-67.
[http://dx.doi.org/10.1016/j.radphyschem.2014.04.023]
[14]
Xu, H.; Suslick, K.S. ACS Nano, 2010, 4(6), 3209-3214.
[http://dx.doi.org/10.1021/nn100987k ] [PMID: 20507161]
[15]
Zain, N.M.; Stapley, A.G.; Shama, G. Carbohydr. Polym., 2014, 112, 195-202.
[http://dx.doi.org/10.1016/j.carbpol.2014.05.081 ] [PMID: 25129735]
[16]
Khan, Z.; Singh, T.; Hussain, J.I.; Obaid, A.Y.; Al-Thabaiti, S.A.; El-Mossalamy, E.H. Colloids Surf. B Biointerfaces, 2013, 102, 578-584.
[http://dx.doi.org/10.1016/j.colsurfb.2012.08.057 ] [PMID: 23104028]
[17]
Venkatesham, M.; Ayodhya, D.; Madhusudhan, A.; Veerabhadram, G. International Journal of Green Nanotechnology, 2012, 4, 199-206.
[http://dx.doi.org/10.1080/19430892.2012.705999]
[18]
Wang, H.; Qiao, X.; Chen, J.; Wang, X.; Ding, S. Mater. Chem. Phys., 2005, 94, 449-453.
[http://dx.doi.org/10.1016/j.matchemphys.2005.05.005]
[19]
Filippo, E.; Serra, A.; Manno, D. Sens. Actuators B Chem., 2009, 138, 625-630.
[http://dx.doi.org/10.1016/j.snb.2009.02.056]
[20]
Abou-Okeil, A. J. Nat. Fibers, 2012, 9, 61-72.
[http://dx.doi.org/10.1080/15440478.2011.651841]
[21]
Cooke, J.; Hebert, D.; Kelly, J.A. J. Chem. Educ., 2014, 92, 345-349.
[http://dx.doi.org/10.1021/ed5004756]
[22]
Odeku, O.A. Starke, 2013, 65, 89-106.
[http://dx.doi.org/10.1002/star.201200076]
[23]
Ali Akbari Ghavimi, S.; Ebrahimzadeh, M.H.; Solati-Hashjin, M.; Abu Osman, N.A. J. Biomed. Mater. Res. A, 2015, 103(7), 2482-2498.
[http://dx.doi.org/10.1002/jbm.a.35371 ] [PMID: 25407786]
[24]
Bertolini, A.C.; Mestres, C.; Colonna, P. Raffi. J. Carbohydr. Polym., 2001, 44, 269-271.
[http://dx.doi.org/10.1016/S0144-8617(00)00268-X]
[25]
Lee, J.S.; Kumar, R.N.; Rozman, H.; Azemi, B. Carbohydr. Polym., 2004, 56, 347-354.
[http://dx.doi.org/10.1016/j.carbpol.2004.03.010]
[26]
Ashogbon, A.O.; Akintayo, E.T. Starke, 2014, 66, 41-57.
[http://dx.doi.org/10.1002/star.201300106]
[27]
El-Sayed, Z.; Fahmy, H.; Ibrahim, N.; Abo-Shosha, M. Egypt. J. Chem., 2004, 47.
[28]
Fahmy, H.; Aly, A.; El-Sayed Mohamed, Z.; Ibrahim, N.; Abo-Shosha, M. Polym. Plast. Technol. Eng., 2006, 45, 49-53.
[http://dx.doi.org/10.1080/03602550500371711]
[29]
Li, H.; Wu, B.; Mu, C.; Lin, W. Carbohydr. Polym., 2011, 84, 881-886.
[http://dx.doi.org/10.1016/j.carbpol.2010.12.026]
[30]
Mu, C.; Guo, J.; Li, X.; Lin, W.; Li, D. Food Hydrocoll., 2012, 27, 22-29.
[http://dx.doi.org/10.1016/j.foodhyd.2011.09.005]
[31]
Fan, Q.; Lewis, D.; Tapley, K. J. Appl. Polym. Sci., 2001, 82, 1195-1202.
[http://dx.doi.org/10.1002/app.1953]
[32]
Ayala Valencia, G.; Cristina de Oliveira Vercik, L.; Ferrari, R.; Vercik, A. Starke, 2013, 65, 931-937.
[http://dx.doi.org/10.1002/star.201200252]
[33]
Jiang, X.C.; Chen, W.M.; Chen, C.Y.; Xiong, S.X.; Yu, A.B. Nanoscale Res. Lett., 2011, 6(1), 32.
[PMID: 27502655]
[34]
Bischof Vukušić, S.; Flinčec Grgac, S.; Budimir, A.; Kalenić, S. Croat. Med. J., 2011, 52(1), 68-75.
[http://dx.doi.org/10.3325/cmj.2011.52.68 ] [PMID: 21328723]
[35]
Nada, A.A.; Soliman, A.A.; Aly, A.A.; Abou‐Okeil, A. Starke, 2019.711800243
[36]
Hou, Q.; Liu, W.; Liu, Z.; Duan, B.; Bai, L. Carbohydr. Polym., 2008, 74, 235-240.
[http://dx.doi.org/10.1016/j.carbpol.2008.02.010]
[37]
Abou-Zeid, N.; Waly, A.; Kandile, N.; Rushdy, A.; El-Sheikh, M.; Ibrahim, H. Carbohydr. Polym., 2011, 84, 223-230.
[http://dx.doi.org/10.1016/j.carbpol.2010.11.026]

Rights & Permissions Print Cite
Article Metrics
24
1
© 2024 Bentham Science Publishers | Privacy Policy