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Current Organic Synthesis


ISSN (Print): 1570-1794
ISSN (Online): 1875-6271

Letter Article

Carboxylate-Functionalized P, N-Ligated Cobalt Catalysts for Alkene Hydrosilylation

Author(s): Yangyang Ma, Jiayun Li*, Ying Bai and Jiajian Peng*

Volume 18, Issue 5, 2021

Published on: 14 December, 2020

Page: [425 - 430] Pages: 6

DOI: 10.2174/1570179417666201214112514


A series of N, P-ligands bearing carboxyl groups have been synthesized. These have been applied in conjunction with cobalt naphthenate in a facile, economic, and efficient method for the catalytic hydrosilylation of alkenes. In the presence of KOtBu as an additive, the reaction time and activation energy are greatly reduced.

Keywords: Cobalt complex, N, P-Ligands, hydrosilylation, alkene, KOtBu, facile.

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