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Current Organic Chemistry

Editor-in-Chief

ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

Review Article (Mini-Review)

Heterogeneous Palladium Catalysts in the Hydrogenation of the Carbon-carbon Double Bond

Author(s): Stanislav A. Grabovskii*, Timur I. Akchurin and Vladimir A. Dokichev

Volume 25 , Issue 2 , 2021

Published on: 01 December, 2020

Page: [315 - 329] Pages: 15

DOI: 10.2174/1385272824999201202084812

Price: $65

Abstract

The results of studies over the past ten years in the field of C=C bond hydrogenation in the presence of palladium catalysts deposited on various inorganic and organic carriers such activated carbons, carbon nanotubes, alumina, zeolites, or composite materials based on Al2O3-SiO2, polystyrene, polypropyleneimine, polyamidoamine and hybrid inorganic/ polymer-carriers, are presented. The selectivity and rates of the hydrogenation process are considered and some comparisons are made. Porous supports and containing dendrimers generally retain palladium particles more effectively. Nanosized palladium stabilized by different dendrimers catalyzes the hydrogenation of C=C bonds in polyfunctional compounds chemoselectively without affecting functional groups, such as CHO, C=O, C(O)OR, CN, NO2, and halogens.

Keywords: Catalysis, hydrogenation, palladium, unsaturated compounds, inorganic carriers, organic carriers.

Graphical Abstract
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