Login Register Cart 0
Generic placeholder image

Current Analytical Chemistry

Editor-in-Chief

ISSN (Print): 1573-4110
ISSN (Online): 1875-6727

Back
Journal Home About Journal Editorial Board Journal Insight Current Issue Volumes/Issues
Subscribe
Research Article

Lead Adsorption in Manganese Oxides as Powders and Coatings Supported on Silica Gel Beads and Tin Inverse Opal-Like Structures

Author(s): Maria Guadalupe Almanza Martínez, José de Jesús Pérez Bueno*, Elizabeth Manríquez Reza and Maria Luisa Mendoza López

Volume 17, Issue 6, 2021

Published on: 16 January, 2020

Page: [831 - 838] Pages: 8

DOI: 10.2174/1573411016666200116095505

Price: $65

Abstract

Background: Pollution in water is of concern because of its negative influence on human health and impact on ecosystems. Three-dimensional (3D) structures in the form of inverse opals and opals-like structures were constructed on a scale of millimeters for their use in the adsorption of heavy metals adsorption on manganese oxide-covered surfaces.

Objective: Manganese oxides both, as commercial powders and as synthesized coatings by the chemical bath method, have a high capacity of lead ions adsorption. The inverse opals and opals-like structures increase the contact area and regulate the flux.

Methods: The chemical bath method was used to coating surfaces of inverse opals and opals-like structures. The size of structures was proposed in millimeters to guarantee an easier flow of water.

Results: The manganese oxide deposits were predominantly constituted by an amorphous phase. The present crystalline forms were identified as γ − MnO2, ε − MnO2, Birnessite, and pyrolusite. The best adsorption was obtained with Mn(II, III) and Mn(II), with 91.4% and 80.6%, respectively.

Conclusion: Mn(II, III) and Mn(II) had approximately three times better performance than oxides of Mn(III), Mn(IV), and chemical bath deposited MnO2 in powder form in the lead adsorption.

Keywords: Inverse opals, lead adsorption, manganese oxide, opals, MnO2, ecosystems.

« Previous Next »
Graphical Abstract

[1]
Meyer, P.A.; Brown, M.J.; Falk, H. Global approach to reducing lead exposure and poisoning. Mutat. Res., 2008, 659(1-2), 166-175.
[http://dx.doi.org/10.1016/j.mrrev.2008.03.003] [PMID: 18436472]
[2]
García-Lestón, J.; Méndez, J.; Pásaro, E.; Laffon, B. Genotoxic effects of lead: an updated review. Environ. Int., 2010, 36(6), 623-636.
[http://dx.doi.org/10.1016/j.envint.2010.04.011] [PMID: 20466424]
[3]
Zhu, Q.; Li, Z. Hydrogel-supported nanosized hydrous manganese dioxide: Synthesis, characterization, and adsorption behavior study for Pb2+, Cu2+, Cd2+ and Ni2+ removal from water. Chem. Eng. J., 2015, 281, 69-80.
[http://dx.doi.org/10.1016/j.cej.2015.06.068]
[4]
Saleh, T.A. Nanocomposite of carbon nanotubes/silica nanoparticles and their use for adsorption of Pb(II): from surface properties to sorption mechanism. Desalin. Water Treat., 2016, 57(23), 10730-10744.
[http://dx.doi.org/10.1080/19443994.2015.1036784]
[5]
Mahmoodi, N.M.; Hosseinabadi-Farahani, Z.; Chamani, H. Nanostructured adsorbent (MnO2): Synthesis and least square support vector machine modeling of dye removal. Desalin. Water Treat., 2016, 57, 21524-21533.
[http://dx.doi.org/10.1080/19443994.2015.1120685]
[6]
Perelomov, L.V.; Sizova, O.I.; Atroshchenko, Y.M. Adsorption of trace elements by bentonite in the presence of bacteria. Geochem. Int., 2019, 57(3), 290-297.
[http://dx.doi.org/10.1134/S001670291903008X]
[7]
Zhang, H.; Gao, Z.; Liu, Y.; Ran, C.; Mao, X.; Kang, Q.; Ao, W.; Fu, J.; Li, J.; Liu, G.; Dai, J. Microwave-assisted pyrolysis of textile dyeing sludge, and migration and distribution of heavy metals. J. Hazard. Mater., 2018, 355, 128-135.
[http://dx.doi.org/10.1016/j.jhazmat.2018.04.080] [PMID: 29783153]
[8]
Li, P.; Wang, J.; Li, X.; Zhu, W.; He, S.; Han, C.; Luo, Y.; Ma, W.; Liu, N.; Dionysiou, D.D. Facile synthesis of amino-functional large-size mesoporous silica sphere and its application for Pb2+ removal. J. Hazard. Mater., 2019, 378120664
[http://dx.doi.org/10.1016/j.jhazmat.2019.05.057]] [PMID: 31203120]
[9]
Radi, S.; Abiad, C.E.; Moura, N.M.M.; Faustino, M.A.F.; Neves, M.G.P.M.S. New hybrid adsorbent based on porphyrin functionalized silica for heavy metals removal: Synthesis, characterization, isotherms, kinetics and thermodynamics studies. J. Hazard. Mater., 2019, 370, 80-90.
[http://dx.doi.org/10.1016/j.jhazmat.2017.10.058] [PMID: 29150138]
[10]
Xia, W.Y.; Du, Y.J.; Li, F.S.; Li, C.P.; Yan, X.L.; Arulrajah, A.; Wang, F.; Song, D.J. In-situ solidification/stabilization of heavy metals contaminated site soil using a dry jet mixing method and new hydroxyapatite based binder. J. Hazard. Mater., 2019, 369, 353-361.
[http://dx.doi.org/10.1016/j.jhazmat.2019.02.031] [PMID: 30784965]
[11]
Zheng, Y.; Cheng, B.; You, W.; Yu, J.; Ho, W. 3D hierarchical graphene oxide-NiFe LDH composite with enhanced adsorption affinity to Congo red, methyl orange and Cr(VI) ions. J. Hazard. Mater., 2019, 369, 214-225.
[http://dx.doi.org/10.1016/j.jhazmat.2019.02.013] [PMID: 30776604]
[12]
Zhang, J.; Xie, X.; Meng, X.; Li, Y.; Zhu, W. Release and transport of Pb(II) adsorbed on graphene oxide under alkaline conditions in a saturated sand column. J. Hazard. Mater., 2019, 377, 357-364.
[http://dx.doi.org/10.1016/j.jhazmat.2019.05.087] [PMID: 31173986]
[13]
Godiya, C.B.; Cheng, X.; Li, D.; Chen, Z.; Lu, X. Carboxymethyl cellulose/polyacrylamide composite hydrogel for cascaded treatment/reuse of heavy metal ions in wastewater. J. Hazard. Mater., 2019, 364, 28-38.
[http://dx.doi.org/10.1016/j.jhazmat.2018.09.076] [PMID: 30336333]
[14]
Mohammadi, Z.; Shangbin, S.; Berkland, C.; Liang, J.T. Chelator-mimetic multi-functionalized hydrogel: Highly efficient and reusable sorbent for Cd, Pb, and As removal from waste water. Chem. Eng. J., 2017, 307, 496-502.
[http://dx.doi.org/10.1016/j.cej.2016.08.121]
[15]
Chen, B.; Fang, L.; Yan, X.; Zhang, A.; Chen, P.; Luan, T.; Hu, L.; Jiang, G. A unique Pb-binding flagellin as an effective remediation tool for Pb contamination in aquatic environment. J. Hazard. Mater., 2019, 363, 34-40.
[http://dx.doi.org/10.1016/j.jhazmat.2018.10.004] [PMID: 30300776]
[16]
Liu, X.; Lai, D.; Wang, Y. Performance of Pb(II) removal by an activated carbon supported nanoscale zero-valent iron composite at ultralow iron content. J. Hazard. Mater., 2019, 361, 37-48.
[http://dx.doi.org/10.1016/j.jhazmat.2018.08.082] [PMID: 30176414]
[17]
Wang, Y.; Gao, S.; Liu, X.; Tang, B.; Mukiza, E.; Zhang, N. Preparation of non-sintered permeable bricks using electrolytic manganese residue: Environmental and NH3-N recovery benefits. J. Hazard. Mater., 2019, 378120768
[http://dx.doi.org/10.1016/j.jhazmat.2019.120768]] [PMID: 31220649]
[18]
Luo, C.; Wei, R.; Guo, D.; Zhang, S.; Yan, S. Adsorption behavior of MnO2 functionalized multi-walled carbon nanotubes for the removal of cadmium from aqueous solutions. Chem. Eng. J., 2013, 225(1), 406-415.
[http://dx.doi.org/10.1016/j.cej.2013.03.128]
[19]
Deng, H.; Wang, Y.; Wu, H.; Liu, T.; Chen, Y. Characteristics of Tl(I) adsorption on γ-MnO2. Huanjing Kexue Yanjiu, 2015, 28(1), 103-109.
[20]
Wang, S.; Gong, W.; Liu, X.; Yao, Y.; Gao, B.; Yue, Q. Removal of lead(II) from aqueous solution by adsorption onto manganese oxide-coated carbon nanotubes. Separ. Purif. Tech., 2007, 58(1), 17-23.
[http://dx.doi.org/10.1016/j.seppur.2007.07.006]
[21]
Taffarel, S.R.; Rubio, J. Removal of Mn2+ from aqueous solution by manganese oxide coated zeolite. Miner. Eng., 2010, 23(14), 1131-1138.
[http://dx.doi.org/10.1016/j.mineng.2010.07.007]
[22]
Han, R.; Zou, W.; Zhang, Z.; Shi, J.; Yang, J. Removal of copper(II) and lead(II) from aqueous solution by manganese oxide coated sand I. Characterization and kinetic study. J. Hazard. Mater., 2006, 137(1), 384-395.
[http://dx.doi.org/10.1016/j.jhazmat.2006.02.021] [PMID: 16603312]
[23]
Dong, L.; Zhu, Z.; Ma, H.; Qiu, Y.; Zhao, J. Simultaneous adsorption of lead and cadmium on MnO2-loaded resin. J. Environ. Sci. (China), 2010, 22(2), 225-229.
[http://dx.doi.org/10.1016/S1001-0742(09)60097-8 ] [PMID: 20397410]
[24]
Ma, Y.; Wang, S.G.; Fan, M.; Gong, W.X.; Gao, B.Y. Characteristics and defluoridation performance of granular activated carbons coated with manganese oxides. J. Hazard. Mater., 2009, 168(2-3), 1140-1146.
[http://dx.doi.org/10.1016/j.jhazmat.2009.02.145] [PMID: 19345485]
[25]
Stein, A.; Wilson, B.E.; Rudisill, S.G. Design and functionality of colloidal-crystal-templated materials--chemical applications of inverse opals. Chem. Soc. Rev., 2013, 42(7), 2763-2803.
[http://dx.doi.org/10.1039/C2CS35317B] [PMID: 23079696]
[26]
Unuma, H.; Kenehama, T.; Yamamoto, K.; Watanabe, K.; Ogata, T.; Sugwara, M. Preparation of thin films of MnO2 and CeO2 by a modified chemical bath (oxidative-soak-coating) method. J. Mater. Sci., 2003, 38(2), 255-259.
[http://dx.doi.org/10.1023/A:1021197029004]
[27]
Roriz, E.R.R.; Espinoza, D.C.R.; Tenório, J.A.S. Battery recycling: Effect of current density on manganese recovery through electrolytic process. Braz. J. Chem. Eng., 2016, 33(2), 271-277.
[http://dx.doi.org/10.1590/0104-6632.20160332s00003588]

Rights & Permissions Print Cite
Article Metrics
21
1
© 2024 Bentham Science Publishers | Privacy Policy