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Current Pharmaceutical Design

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ISSN (Print): 1381-6128
ISSN (Online): 1873-4286

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Review Article

Core-Shell Molecularly Imprinted Polymer Nanocomposites for Biomedical and Environmental Applications

Author(s): Nasrullah Shah*, Saba Gul and Mazhar Ul-Islam*

Volume 25, Issue 34, 2019

Page: [3633 - 3644] Pages: 12

DOI: 10.2174/1381612825666191009153259

Price: $65

Abstract

Core-shell polymers represent a class of composite particles comprising of minimum two dissimilar constituents, one at the center known as a core which is occupied by the other called shell. Core-shell molecularly imprinting polymers (CSMIPs) are composites prepared via printing a template molecule (analyte) in the coreshell assembly followed by their elimination to provide the everlasting cavities specific to the template molecules. Various other types of CSMIPs with a partial shell, hollow-core and empty-shell are also prepared. Numerous methods have been reported for synthesizing the CSMIPs. CSMIPs composites could develop the ability to identify template molecules, increase the relative adsorption selectivity and offer higher adsorption capacity. Keen features are measured that permits these polymers to be utilized in numerous applications. It has been developed as a modern technique with the probability for an extensive range of uses in selective adsorption, biomedical fields, food processing, environmental applications, in utilizing the plant's extracts for further applications, and sensors. This review covers the approaches of developing the CSMIPs synthetic schemes, and their application with special emphasis on uses in the biomedical field, food care subjects, plant extracts analysis and in environmental studies.

Keywords: Core-shell MIPs, synthesis, applications, biomedical, environmental, CSMIPs composites.

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[http://dx.doi.org/10.1016/j.carbpol.2016.09.078] [PMID: 27987930]
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[http://dx.doi.org/10.5004/dwt.2018.23230]
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[http://dx.doi.org/10.2174/1872210510666160429145704] [PMID: 27136927]
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Kamal T, Anwar Y, Khan SB, Chani MTS, Asiri AM. Dye adsorption and bactericidal properties of TiO2/chitosan coating layer. Carbohydr Polym 2016; 148: 153-60.
[http://dx.doi.org/10.1016/j.carbpol.2016.04.042] [PMID: 27185126]
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Kamal T, Khan SB, Asiri AM. Synthesis of zero-valent Cu nanoparticles in the chitosan coating layer on cellulose microfibers: evaluation of azo dyes catalytic reduction. Cellulose 2016; 23: 1911-23.
[http://dx.doi.org/10.1007/s10570-016-0919-9]
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Kamal T, Khan SB, Asiri AM. Nickel nanoparticles-chitosan composite coated cellulose filter paper: an efficient and easily recoverable dip-catalyst for pollutants degradation. Environ Pollut 2016; 218: 625-33.
[http://dx.doi.org/10.1016/j.envpol.2016.07.046] [PMID: 27481647]
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Kamal T, Khan SB, Haider S, Alghamdi YG, Asiri AM. Thin layer chitosan-coated cellulose filter paper as substrate for immobilization of catalytic cobalt nanoparticles Int J Biol Macromol 2017; 104(Pt A): 56-62.
[http://dx.doi.org/10.1016/j.ijbiomac.2017.05.157] [PMID: 28571736]
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Kamal T, Ul-Islam M, Khan SB, Asiri AM. Adsorption and photocatalyst assisted dye removal and bactericidal performance of ZnO/chitosan coating layer. Int J Biol Macromol 2015; 81: 584-90.
[http://dx.doi.org/10.1016/j.ijbiomac.2015.08.060] [PMID: 26321421]
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Khan FU. Asimullah , Khan SB, et al. Novel combination of zero-valent Cu and Ag nanoparticles @ cellulose acetate nanocomposite for the reduction of 4-nitro phenol. Int J Biol Macromol 2017; 102: 868-77.
[http://dx.doi.org/10.1016/j.ijbiomac.2017.04.062] [PMID: 28428128]
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Khan MSJ, Kamal T, Ali F, Asiri AM, Khan SB. Chitosan-coated polyurethane sponge supported metal nanoparticles for catalytic reduction of organic pollutants. Int J Biol Macromol 2019; 132: 772-83.
[http://dx.doi.org/10.1016/j.ijbiomac.2019.03.205] [PMID: 30928377]
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Khan SA, Khan SB, Kamal T, Yasir M, Asiri AM. Antibacterial nanocomposites based on chitosan/Co-MCM as a selective and efficient adsorbent for organic dyes. Int J Biol Macromol 2016; 91: 744-51.
[http://dx.doi.org/10.1016/j.ijbiomac.2016.06.018] [PMID: 27287771]
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Khan SB, Ali F, Kamal T, Anwar Y, Asiri AM, Seo J. CuO embedded chitosan spheres as antibacterial adsorbent for dyes. Int J Biol Macromol 2016; 88: 113-9.
[http://dx.doi.org/10.1016/j.ijbiomac.2016.03.026] [PMID: 26993528]
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[http://dx.doi.org/10.1039/C6RA21626A]
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[http://dx.doi.org/10.1016/j.molstruc.2018.11.030]
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Ahmad I, Khan SB, Kamal T, Asiri AM. Visible light activated degradation of organic pollutants using zinc-iron selenide. J Mol Liq 2017; 229: 429-35.
[http://dx.doi.org/10.1016/j.molliq.2016.12.061]
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Ali N, Ismail M, Khan A, Khan H, Haider S, Kamal T. Spectrophotometric methods for the determination of urea in real samples using silver nanoparticles by standard addition and 2nd order derivative methods. Spectrochim Acta A Mol Biomol Spectrosc 2018; 189: 110-5.
[105]
Chani MTS, Karimov KS, Khan SB, Kamal T, Asiri AM. Synthesis and pressure sensing properties of pristine zinc oxide nanopowder and its blend with carbon nanotubes. Curr Nanosci 2016; 12: 586-91.
[http://dx.doi.org/10.2174/1573413712666160502123744]
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Kamal T. High performance NiO decorated graphene as a potential H-2 gas sensor. J Alloys Compd 2017; 729: 1058-63.
[http://dx.doi.org/10.1016/j.jallcom.2017.09.124]
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Kavitha T, Kumar S, Prasad V, Asiri AM, Kamal T, Ul-Islam M. NiO powder synthesized through nickel metal complex degradation for water treatment. Desalination Water Treat 2019; 155: 216-24.
[http://dx.doi.org/10.5004/dwt.2019.24054]
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Luo X, Zhan Y, Huang Y, Yang L, Tu X, Luo S. Removal of water-soluble acid dyes from water environment using a novel magnetic molecularly imprinted polymer. J Hazard Mater 2011; 187(1-3): 274-82.
[http://dx.doi.org/10.1016/j.jhazmat.2011.01.009] [PMID: 21269767]
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Gao R, Kong X, Su F, He X, Chen L, Zhang Y. Synthesis and evaluation of molecularly imprinted core-shell carbon nanotubes for the determination of triclosan in environmental water samples. J Chromatogr A 2010; 1217(52): 8095-102.
[http://dx.doi.org/10.1016/j.chroma.2010.10.121] [PMID: 21093867]

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