Synthesis and Characterization of Chitosan-Ferrocenylimine Palladacycle and its Catalytic Performance in Heck Reaction

Author(s): Yonghuan Yang, Guanghua Li, Ziwei Song, Xinli Yang, Pu Liu

Journal Name: Letters in Organic Chemistry

Volume 7 , Issue 7 , 2010

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Abstract:

Chitosan-ferrocenylimine palladacycle complex (CS-Fe-Pd) was synthesized in a simple way and characterized by FT-IR, XRD, XPS and TG-DSC. Using CS-Fe-Pd as catalyst, it showed a highly catalytic activity and stereoselectivity to the coupling product in Heck reaction about the arylation of conjugate alkene with aryl halide. This chitosan-supported ferrocenylimine palladacycle catalyst can be recovered easily and reused at least for four cycles with high yield.

Keywords: Chitosan, ferrocenylimine, catalyst, palladacycle, heck reaction, CS-Fe-Pd, FT-IR, XRD, XPS, TG-DSC, chitin, palladium, HITACHIZ-8000 atomic absorption spectroscopy, calorimeter, gas chromatography, X-ray, NMR, olefin, aryl iodide, arylation reaction, iodobenzene, acrylamide, TLC, thin layer chromatography

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Article Details

VOLUME: 7
ISSUE: 7
Year: 2010
Page: [533 - 538]
Pages: 6
DOI: 10.2174/157017810793362316
Price: $65

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