Abstract
The asymmetric hydrosilylation of ketones and imines has seen significant advances in the last decade. The discovery of new highly efficient catalysts has turned this catalytic process into an attractive method for practical applications. Impressive chemical yields and enantioselectivities have been attained employing newly designed catalytic systems based on rhodium, copper, zinc and iron with suitable bidentate chiral ligands.
Keywords: Asymmetric catalysis, hydrosilylation, alcohols-amines, ketones, amines
Mini-Reviews in Organic Chemistry
Title: Recent Progress in the Asymmetric Hydrosilylation of Ketones and Imines
Volume: 6 Issue: 3
Author(s): Carmela G. Arena
Affiliation:
Keywords: Asymmetric catalysis, hydrosilylation, alcohols-amines, ketones, amines
Abstract: The asymmetric hydrosilylation of ketones and imines has seen significant advances in the last decade. The discovery of new highly efficient catalysts has turned this catalytic process into an attractive method for practical applications. Impressive chemical yields and enantioselectivities have been attained employing newly designed catalytic systems based on rhodium, copper, zinc and iron with suitable bidentate chiral ligands.
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Arena G. Carmela, Recent Progress in the Asymmetric Hydrosilylation of Ketones and Imines, Mini-Reviews in Organic Chemistry 2009; 6 (3) . https://dx.doi.org/10.2174/157019309788922766
DOI https://dx.doi.org/10.2174/157019309788922766 |
Print ISSN 1570-193X |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6298 |
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