Utilization of Phenyl Trialkylstannyl Selenide as a Promising Reagent for Introduction of the Phenylseleno Group

Author(s): Yutaka Nishiyama, Noboru Sonoda

Journal Name: Mini-Reviews in Organic Chemistry

Volume 2 , Issue 2 , 2005


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Abstract:

New synthetic methods of organoselenium compounds by the use of phenyl tributylstannyl selenide (PhSeSnBu3) (1), which is a stable selenium reagent in air and moisture, as a phenylselenated reagent have been developed. In the presence of palladium complex catalyst, the reaction of 1 with organohalogen compounds took place efficiently to give the corresponding organoselenium compounds in moderate to good yields. Furthermore, it was found that Lewis acid assisted the reaction of 1 with oxygen-containing compounds giving the corresponding organoselenium compounds.

Keywords: phenyl tributylstannyl selenide, palladium catalyst, organoselenium compound, lewis acid, aryl halide, aroyl halide, carbon monoxide, bromo ketone, acetal, epoxide

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Article Details

VOLUME: 2
ISSUE: 2
Year: 2005
Page: [147 - 155]
Pages: 9
DOI: 10.2174/1570193053544463
Price: $65

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