Abstract
Suitable electrochemical methodologies for the generation of cyanomethyl anion and some electrochemically induced cyanomethylation reactions of electrophilic substrates are described and discussed. In addition, the electrochemical syntheses of carbamates and chiral oxazolidin-2-ones (under mild conditions and avoiding the use of hazardous chemicals), via a new carboxylating reagent (CH2CN- / CO2), are reported in this article.
Keywords: cyanomethyl anion, organic electrosyntheses, cyanomethylation reactions, chiral oxazolidinones, carbamates, carboxylating reactions
Mini-Reviews in Organic Chemistry
Title: The Electrogenerated Cyanomethyl Anion in Organic Synthesis
Volume: 2 Issue: 1
Author(s): L. Rossi, M. Feroci and A. Inesi
Affiliation:
Keywords: cyanomethyl anion, organic electrosyntheses, cyanomethylation reactions, chiral oxazolidinones, carbamates, carboxylating reactions
Abstract: Suitable electrochemical methodologies for the generation of cyanomethyl anion and some electrochemically induced cyanomethylation reactions of electrophilic substrates are described and discussed. In addition, the electrochemical syntheses of carbamates and chiral oxazolidin-2-ones (under mild conditions and avoiding the use of hazardous chemicals), via a new carboxylating reagent (CH2CN- / CO2), are reported in this article.
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Cite this article as:
Rossi L., Feroci M. and Inesi A., The Electrogenerated Cyanomethyl Anion in Organic Synthesis, Mini-Reviews in Organic Chemistry 2005; 2 (1) . https://dx.doi.org/10.2174/1570193052774135
DOI https://dx.doi.org/10.2174/1570193052774135 |
Print ISSN 1570-193X |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6298 |
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