Isolable 1,2-Oxaphosphetanes: From Curiosities to Starting Materials for the Synthesis of Olefins

Author(s): Fernando Lopez-Ortiz, Jesus Garcia Lopez, Ramon Alvarez Manzaneda, Isidro J. Perez Alvarez

Journal Name: Mini-Reviews in Organic Chemistry

Volume 1 , Issue 1 , 2004

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Abstract:

1,2-Oxaphosphetanes are well established intermediate species in the Wittig reaction. Initially, isolable 1,2-oxaphosphetanes represented a source of structural information aimed at supporting mechanistic studies. The evolution of the subject allows the envisaging of stable 1,2-oxaphosphetanes as precursors for the stereoselective formation of olefins.

Keywords: oxaphosphetanes, olefination, wittig, spiro-heterocycles, phosphorus ylides, phosphazenes

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Article Details

VOLUME: 1
ISSUE: 1
Year: 2004
Page: [65 - 70]
Pages: 6
DOI: 10.2174/1570193043488962

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