Palladium-Catalyzed Allylic Substitution Reaction in Polymer Synthesis

Author(s): N. Nomura, K. Tsurugi, N. Yoshida, M. Okada

Journal Name: Current Organic Synthesis

Volume 2 , Issue 1 , 2005

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Polymer synthesis via the palladium-catalyzed allylic substitution reaction between allylic esters and malonic esters, namely the Tsuji-Trost reaction, is summarized in this review. Due to the versatility and potential of the Tsuji-Trost reaction, four polymerization patterns for various functionalized polymers have been reported.

Keywords: tsuji-trost reaction, allylpalladium, polymerization, allylation, palladium, polymer synthesis

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Article Details

Year: 2005
Page: [21 - 38]
Pages: 18
DOI: 10.2174/1570179052996973

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PDF: 27