4H-Thiopyran-1-Oxides. Photochemical Deoxygenation and Oxenoid Reactivity

Author(s): Farnaz Jafarpour, Hooshang Pirelahi

Journal Name: Letters in Organic Chemistry

Volume 3 , Issue 2 , 2006


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Abstract:

Upon UV-irradiation in chloroform solution, some of the 2,4,4,6-tetrasubstituted-4H-thiopyran-1-oxides underwent deoxygenation to give the corresponding 4H-thiopyrans in good yields together with the corresponding 4Hthiopyran- 1,1-dioxides as minor components. Moreover, in benzene as an aromatic solvent oxenoid functionalization was observed.

Keywords: 4H-Thiopyran-1-oxides, photodeoxygenation, oxenoid functionalization

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Article Details

VOLUME: 3
ISSUE: 2
Year: 2006
Page: [115 - 117]
Pages: 3
DOI: 10.2174/157017806775224242
Price: $65

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