Stereoselective Total Synthesis of (+)-Sedamine

Author(s): Jagat C. Borah, Joshodeep Boruwa, Nabin C. Barua

Journal Name: Letters in Organic Chemistry

Volume 3 , Issue 2 , 2006


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Abstract:

A highly efficient stereoselective total synthesis of piperidine alkaloid (+)-sedamine has been described utilizing two regioselective ring opening reactions of epoxide with vinyl metallic reagent and a ring closing metathesis reaction as the key steps.

Keywords: (+)-sedamine, vinylmetallic reagent, ADH, regioselective epoxide opening, RCM

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Article Details

VOLUME: 3
ISSUE: 2
Year: 2006
Page: [140 - 142]
Pages: 3
DOI: 10.2174/157017806775224297
Price: $65

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