Recent Developments on the Carbamation of Amines

Author(s): Devdutt Chaturvedi

Journal Name: Current Organic Chemistry

Volume 15 , Issue 10 , 2011


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Abstract:

Organic carbamates represent an important class of compounds showing various interesting properties. They find wide utility in various areas as pharmaceuticals, agrochemicals (pesticides, herbicides, insecticides, fungicides etc.), intermediates in organic synthesis, protection of amino group in peptide chemistry, and as linker in combinatorial chemistry etc. Classical synthesis of carbamates involves use of harmful reagents such as phosgene, its derivatives and carbon monoxide. Recently, various kinds of synthetic methods have been developed for the synthesis of organic carbamates. In the present review, I would like to highlight the recent developments on the synthesis of organic carbamates using variety of reagents.

Keywords: Carbamation, amines, carbamates, Phosgenation Technique, Nitro-aromatics, Electrochemical Carbon Dioxide, nbutylammonium iodide, ossen rearrangement, Curtius Rearrangement, Hoffmann Rearrangement, Carbon-Imido Dithiolates, Dithiocarbamates/Thiocarbamates

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Article Details

VOLUME: 15
ISSUE: 10
Year: 2011
Page: [1593 - 1624]
Pages: 32
DOI: 10.2174/138527211795378173
Price: $65

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