Study on the Fluorine-Containing Reactive Intermediates and Their Application in the Organic Synthesis

Author(s): S. Z. Zhu, P. He

Journal Name: Current Organic Chemistry

Volume 8 , Issue 2 , 2004

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This review deals with recent progress concerning the preparations, reactions, mechanisms and synthetic applications of some precursor compounds of the fluorine-containing reactive intermediates, such as phenyliodonium bis (perfluoro alkanesulfonyl) methides, PhI+--C(SO2Rf)2; perfluoroalkanesulfonyl azides, RfSO2N3 N,N-dichloro perfluoroalkanesulfonyl amides, RfSO2NCl2, aryldiazonium bis(perfluoro alkanesulfonyl) methides, ArN2 +--CH(SO2Rf)2, aryldiazonium bis(perfluoroalkanesulfonyl) imides, ArN2 +--N(SO2Rf)2 N-sulfinyl per- (or) polyfluoroalkanesulfonyl amides, RfSO2N=S=O, N-sulfinyl per- (or) polyfluorophenylaniline, ArFN=S=O. Under mild reaction conditions they react readily with many organic reagents to give various fluorine-containing products.

Keywords: Fluorine, phenyliodonium, polyfluorophenylaniline, N-sulfinyl

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Article Details

Year: 2004
Page: [97 - 112]
Pages: 16
DOI: 10.2174/1385272043486034
Price: $58

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