Abstract
Native and modified cyclodextrins (CDs) have been shown to dramatically affect the properties of guest molecules solubilized within the relatively hydrophobic interior. By monitoring changes in photophysical processes, researchers have been able to determine the stoichiometry and association constants of the resulting complexes. In addition, chemical modification of the CD structure as well as the selective binding of analytes within the CD cavity has lead to remarkable advances in analytical and environmental applications of CDs. In this review, we discuss a selection of fundamental studies performed in our laboratory, primarily using fluorescence spectroscopy as a tool to study the properties of CD host-guest complexes. In addition, this review includes recent studies conducted in other laboratories which are concerned with exploiting the unique properties of CDs and their inclusion complexes in order to study energy transfer through the use of photochemical antennas as well as the development of chemical and environmental sensors.
Keywords: Cyclodextrin, Fluorescence, Host-guest inclusion complex, Ternary, Multichromophoric, Antenna, Sensor, Pesticide, Insecticide, Herbicide
Current Analytical Chemistry
Title: Cyclodextrins Host- Guest Chemistry in Analytical and Environmental Chemistry
Volume: 3 Issue: 3
Author(s): Sayo O. Fakayode, Mark Lowry, Kristin A. Fletcher, Xiaodong Huang, Aleeta M. Powe and Isiah M. Warner
Affiliation:
Keywords: Cyclodextrin, Fluorescence, Host-guest inclusion complex, Ternary, Multichromophoric, Antenna, Sensor, Pesticide, Insecticide, Herbicide
Abstract: Native and modified cyclodextrins (CDs) have been shown to dramatically affect the properties of guest molecules solubilized within the relatively hydrophobic interior. By monitoring changes in photophysical processes, researchers have been able to determine the stoichiometry and association constants of the resulting complexes. In addition, chemical modification of the CD structure as well as the selective binding of analytes within the CD cavity has lead to remarkable advances in analytical and environmental applications of CDs. In this review, we discuss a selection of fundamental studies performed in our laboratory, primarily using fluorescence spectroscopy as a tool to study the properties of CD host-guest complexes. In addition, this review includes recent studies conducted in other laboratories which are concerned with exploiting the unique properties of CDs and their inclusion complexes in order to study energy transfer through the use of photochemical antennas as well as the development of chemical and environmental sensors.
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Cite this article as:
Sayo O. Fakayode , Mark Lowry , Kristin A. Fletcher , Xiaodong Huang , Aleeta M. Powe and Isiah M. Warner , Cyclodextrins Host- Guest Chemistry in Analytical and Environmental Chemistry, Current Analytical Chemistry 2007; 3 (3) . https://dx.doi.org/10.2174/157341107781023811
DOI https://dx.doi.org/10.2174/157341107781023811 |
Print ISSN 1573-4110 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6727 |
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