Bis(allyl)-Ruthenium(IV) Complexes: Promising Precursors for Catalytic Organic Synthesis

Author(s): Jose Gimeno, Pascale Crochet, Sergio E. Garcia-Garrido, Victorio Cadierno

Journal Name: Current Organic Chemistry

Volume 10 , Issue 2 , 2006

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Abstract:

The present review reports on the chemistry of the bis(allyl)-ruthenium(IV) complexes [{Ru(η3:η3-C10H16)(μ- Cl)Cl}2] (C10H16 = 2,7-dimethylocta-2,6-diene-1,8-diyl) and [Ru(η:η2:η-C12H18)Cl2] (C12H18 = dodeca-2,6,10-triene- 1,12-diyl). Stoichiometric reactions allowing the preparation of a variety of organoruthenium(IV) and (II) derivatives, as well as the involvement of these species in a series of catalytic organic transformations are presented.

Keywords: Polymerization, Butadiene, cyclopentadiene, mononuclear neutral complexes, acetonitrile

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Article Details

VOLUME: 10
ISSUE: 2
Year: 2006
Page: [165 - 183]
Pages: 19
DOI: 10.2174/138527206775192933
Price: $58

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