New Method for Determination of Trans-resveratrol for Quality Evaluation of Red Wines by Multivariate Calibration Associated with UVVIS Spectroscopy

Author(s): Milleno D. Mota, Marilena Meira, Juceni P. David*, Erika M. de Oliveira Ribeiro, Hugo N. Brandão, Ademir E. do Vale, Jorge M. David*

Journal Name: Current Analytical Chemistry

Volume 17 , Issue 7 , 2021


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Graphical Abstract:


Abstract:

Background: This work describes a fast, simple, sensitive, and low-cost method for the identification of resveratrol in different brands and varieties of red wines.

Methods: It was developed based on a comparison of the UV-VIS spectra of the samples and samples enriched with different concentrations of the trans-resveratrol standard. The spectra were analyzed by chemometric principal component analysis (PCA) and multivariate calibration.

Results: The PCA data indicated that only 4 main components made possible group samples based on the grape variety characteristics and/or production region.

Conclusion: From the construction of partial least squares (PLS) and multiple linear regression (RLM) models, it was possible to predict the sample trans-resveratrol content with that sample showing similarities between the groups observed in the PCA and the samples used in the model constructions. The predicted trans-resveratrol present in these samples ranged from 0.29 to 23.3 mg L-1. This multivariate method suggested a good predictive capacity of determination of resveratrol concentrations in commercial red wines.

Keywords: Multivariate methods, PCA, PLS, red wine, trans-resveratrol, UV-Vis.

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Article Details

VOLUME: 17
ISSUE: 7
Year: 2021
Published on: 29 December, 2020
Page: [1037 - 1043]
Pages: 7
DOI: 10.2174/1573411017666201229142412

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