Carboxylate-Functionalized P, N-Ligated Cobalt Catalysts for Alkene Hydrosilylation

Author(s): Yangyang Ma, Jiayun Li*, Ying Bai, Jiajian Peng*

Journal Name: Current Organic Synthesis

Volume 18 , Issue 5 , 2021


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Abstract:

A series of N, P-ligands bearing carboxyl groups have been synthesized. These have been applied in conjunction with cobalt naphthenate in a facile, economic, and efficient method for the catalytic hydrosilylation of alkenes. In the presence of KOtBu as an additive, the reaction time and activation energy are greatly reduced.

Keywords: Cobalt complex, N, P-Ligands, hydrosilylation, alkene, KOtBu, facile.

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Article Details

VOLUME: 18
ISSUE: 5
Year: 2021
Published on: 13 December, 2020
Page: [425 - 430]
Pages: 6
DOI: 10.2174/1570179417666201214112514

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