Title:Utilisation of Biomass and Hybrid Biochar from Elephant Grass and Low Density Polyethylene for the Competitive Adsorption of Pb(II), Cu(II), Fe(II) and Zn(II) from Aqueous Media
VOLUME: 14 ISSUE: 2
Author(s):Joshua O. Ighalo*, Lois T. Arowoyele, Samuel Ogunniyi, Comfort A. Adeyanju, Folasade M. Oladipo-Emmanuel, Olayiwola R. Belgore, Maroof O. Omisore and Adewale George Adeniyi*
Affiliation:Department of Chemical Engineering, Faculty of Engineering and Technology, University of Ilorin, Ilorin, P. M. B. 1515, Department of Chemical Engineering, Faculty of Engineering and Technology, University of Ilorin, Ilorin, P. M. B. 1515, Department of Chemical Engineering, Faculty of Engineering and Technology, University of Ilorin, Ilorin, P. M. B. 1515, Department of Chemical Engineering, Faculty of Engineering and Technology, University of Ilorin, Ilorin, P. M. B. 1515, Department of Chemical Engineering, Faculty of Engineering and Technology, University of Ilorin, Ilorin, P. M. B. 1515, Department of Chemical Engineering, Faculty of Engineering and Technology, University of Ilorin, Ilorin, P. M. B. 1515, Department of Chemical Engineering, Faculty of Engineering and Technology, University of Ilorin, Ilorin, P. M. B. 1515, Department of Chemical Engineering, Faculty of Engineering and Technology, University of Ilorin, Ilorin, P. M. B. 1515
Keywords:Competitive adsorption, biochar, elephant grass, heavy metals, isotherm, kinetics.
Abstract:
Background: There are different types of pollutants in water hence they are
constantly in competition for active sites during the adsorption process. A key advantage
of competitive adsorption studies is that these inform regarding the adsorbent’s performance
in real water treatment applications.
Objective: This study aims to investigate the competitive adsorption of Pb(II), Cu(II),
Fe(II) and Zn(II) using elephant grass (Pennisetum purpureum) biochar and hybrid biochar
from LDPE.
Method: The produced biochar was characterised by Scanning Electron Microscopy
(SEM) and Fourier Transform Infrared Spectroscopy (FTIR). The adsorption parameters,
equilibrium isotherm modelling and parametric studies were conducted based on data
from the batch adsorption experiments.
Results: For both adsorbents, the removal efficiency was >99% over the entire investigation
for dosage and contact time, suggesting that they are very efficient for removing multiple
heavy metals from aqueous media. It was observed that removal efficiency was optimal
at 2 g/l dosage and contact time was 20 minutes for both adsorbent types. The Elovich
isotherm and the pseudo-second order kinetic models were best-fit for the competitive
adsorption process.
Conclusion: The study was able to successfully reveal that biomass biochar from elephant
grass and hybrid biochar from LDPE can be used as effective adsorbent material for
the removal of heavy metals from aqueous media. This study bears a positive implication
for environmental protection and solid waste management.
