Formation of Carbon-Oxygen Bond Mediated by Hypervalent Iodine Reagents Under Metal-Free Conditions

Author(s): Ayesha Jalil, Yaxin O. Yang, Zhendong Chen, Rongxuan Jia, Tianhao Bi, Xuemin Li, Yunfei Du*

Journal Name: Mini-Reviews in Organic Chemistry

Volume 18 , Issue 5 , 2021


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Abstract:

Hypervalent iodine reagents are a class of non-metallic oxidants that have been widely used in the construction of several sorts of bond formations. This surging interest in hypervalent iodine reagents is essentially due to their very useful oxidizing properties, combined with their benign environmental character and commercial availability from the past few decades ago. Furthermore, these hypervalent iodine reagents have been used in the construction of many significant building blocks and privileged scaffolds of bioactive natural products. The purpose of writing this review article is to explore all the transformations in which carbon-oxygen bond formation occurs by using hypervalent iodine reagents under metal-free conditions.

Keywords: Dess-Martin periodinane, C-O bond formation, dichloroiodobenzene, hypervalent iodine reagent, metal-free conditions, oxidation.

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Article Details

VOLUME: 18
ISSUE: 5
Year: 2021
Published on: 07 August, 2020
Page: [540 - 605]
Pages: 66
DOI: 10.2174/1570193X17999200807140943
Price: $65

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