CO Surrogates: A Green Alternative in Palladium-Catalyzed CO Gas Free Carbonylation Reactions

Author(s): Mayur V. Khedkar*, Shoeb R. Khan*, Trimurti L. Lambat*, Ratiram G. Chaudhary, Ahmed A. Abdala*

Journal Name: Current Organic Chemistry

Volume 24 , Issue 22 , 2020


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Abstract:

Carbonylation reactions with carbon monoxide (CO) provide efficient and attractive routes for the synthesis of bulk and fine chemicals. However, the practice of using a large excess of an inflammable, lethal and greenhouse CO gas is always a concern in this chemistry. The development of CO surrogates has gained substantial interest and become a green alternative to gaseous CO. Many of the recent studies have focused on the development of other benign and safe reagents to work as a CO source in carbonylation reactions, and the assortment of feasible CO surrogates for specific reaction can be accomplished by the literature data. This review describes the recent developments in palladium-catalyzed carbonyl insertions without the direct use of gaseous CO.

Keywords: Palladium, heterogeneous and homogeneous catalysis, coupling reaction, CO surrogates, carbonylation, CO gas free, green synthesis.

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Article Details

VOLUME: 24
ISSUE: 22
Year: 2020
Published on: 18 December, 2020
Page: [2588 - 2600]
Pages: 13
DOI: 10.2174/1385272824999200622115655
Price: $58

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