2,5-Dihydroxyterephthalic Acid Accelerated Cu(NO3)2.3H2O-Catalyzed Homocoupling Reaction of Arylboronic Acids

Author(s): Fengtian Wu, Chenlong Nan, Jianwei Xie, Mingyang Ma*

Journal Name: Letters in Organic Chemistry

Volume 17 , Issue 11 , 2020

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Graphical Abstract:


A catalyst system derived from commercially available Cu(NO3)2.3H2O and 2,5- dihydroxyterephthalic acid is applied to the homocoupling reaction of arylboronic acids. This transformation provides a convenient approach to symmetrical biaryls with good to excellent yields (39%- 95%), and exhibits good functional group compatibility. Furthermore, biaryl can be prepared in gram quantities in good yield.

Keywords: Arylboronic acid, biaryl, ligand, copper, homocoupling reaction, acid.

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Article Details

Year: 2020
Page: [877 - 883]
Pages: 7
DOI: 10.2174/1570178617666200210110041
Price: $65

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