Synthesis of (E)-1,2-Bis[4-[di(1H-pyrrol-2-yl)methyl]phenyl]ethene as a New Bis(dipyrromethane) Building Block

Author(s): Faride Ranjbari, Salar Hemmati*, Mohammad Reza Rashidi

Journal Name: Letters in Organic Chemistry

Volume 17 , Issue 10 , 2020

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Abstract:

Dipyrromethanes are useful intermediates in the synthesis of porphyrins and their analogs. In this paper, we report the synthesis of a new bis(dipyrromethane) {(E)-1,2-bis[4-[di(1H-pyrrol-2- yl)methyl]phenyl]ethene}, from (E)-4,4'-1,2-ethenediylbis(benzaldehyde), showing a long resonance chain with improved UV spectrometric properties. This product has high potential in the synthesis of new bis(porphyrins) or other related compounds.

Keywords: Aldehydes, bis(dipyrromethanes), bis(porphyrins), dipyrromethanes, porphyrins, pyrrole.

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Article Details

VOLUME: 17
ISSUE: 10
Year: 2020
Page: [794 - 799]
Pages: 6
DOI: 10.2174/1570178617666200207102604
Price: $95

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