Application of Amine-based Ru Compounds in the Olefin Metathesis of Methyl Eugenol: A Comparison with Grubbs Catalysts

Author(s): Denise A. Sousa, Paulo S. Meneses, Patrik D.S. Gois, Eliada A. Silva, Valdemiro P.C. Junior, Benedito S. Lima-Neto, José L. Silva Sá*

Journal Name: Letters in Organic Chemistry

Volume 17 , Issue 8 , 2020

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Abstract:

Methyl eugenol olefin metathesis was conducted with non-carbene Ru-complexes ([RuCl2(PPh3)2amine]) in the absence and presence of SnCl2 or CuCl2 as additives and their catalytic activities were compared with that of a commercial Grubbs catalyst 2nd Generation (G2).

Keywords: Olefin metathesis, Methyl-eugenol, SnCl2, CuCl2, ruthenium, additives.

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Article Details

VOLUME: 17
ISSUE: 8
Year: 2020
Page: [596 - 602]
Pages: 7
DOI: 10.2174/1570178617666191127102552
Price: $65

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