Generic placeholder image

Letters in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

Research Article

Envirocat EPZ-10: An Efficient Catalyst for the Synthesis of 1,2,4- Triazolidine-3-thiones

Author(s): Pradeep M. Mhaldar and Dattaprasad M. Pore*

Volume 17, Issue 4, 2020

Page: [321 - 326] Pages: 6

DOI: 10.2174/1570178616666191019144317

Price: $65

Abstract

A simple and environmentally benign room temperature synthesis of 1,2,4-triazolidine-3- thiones is described using Envirocat EPZ-10R as a solid acid catalyst in the aqueous medium. The use of Envirocat EPZ-10R as a green catalyst, reusability of the catalyst, water as a universal solvent and good yields of the product are the attractive features of the present method.

Keywords: Clay, 1, 2, 4-triazolidine-3-thiones, envirocat EPZ-10R, thiosemicarbazide, water, reusability.

« Previous
Graphical Abstract
[1]
Shaikh, T.S. Undale, K.A.; Gaikwad, D.S.; Pore, D.M.; C.R. Chimi., 2011, 14, 987-990.
[http://dx.doi.org/10.1016/j.crci.2011.08.002]
[2]
Barlow, S.J.; Bastock, T.W.; Clark, J.H.; Cutter, S.R. Tetrahedron Lett., 1993, 34, 3339-3342.
[http://dx.doi.org/10.1016/S0040-4039(00)73698-7]
[3]
Reddy, C.R.; Bhata, Y.S.; Nagendrappa, G.; Jai Prakash, B.S. Catal. Today, 2009, 141, 157-162.
[http://dx.doi.org/10.1016/j.cattod.2008.04.004]
[4]
Lee, K.Y.; Ko, K.Y. Bull. Korean Chem. Soc., 2004, 25, 1929-1933.
[http://dx.doi.org/10.5012/bkcs.2004.25.12.1929]
[5]
Bandgar, B.P.; Uppalla, L.S.; Kurule, D.S. Green Chem., 1999, 1, 243-245.
[http://dx.doi.org/10.1039/a905811g]
[6]
Bandgar, B.P.; Makone, S.S.; Kulkarni, S.R. Monatsh. Chem., 2000, 131, 417-420.
[http://dx.doi.org/10.1007/PL00010311]
[7]
Pore, D.M.; Shaikh, T.S.; Patil, N.G.; Dongare, S.B.; Desai, U.V. Syn. Comm., 2010, 40, 2215-2219.
[http://dx.doi.org/10.1080/00397910903221027]
[8]
Brockunier, L.L.; Parmee, E.R.; Ok, H.O.; Candelore, M.R.; Cascieri, M.A.; Colwell, L.F., Jr; Deng, L.; Feeney, W.P.; Forrest, M.J.; Hom, G.J.; MacIntyre, D.E.; Tota, L.; Wyvratt, M.J.; Fisher, M.H.; Weber, A.E. Bioorg. Med. Chem. Lett., 2000, 10(18), 2111-2114.
[http://dx.doi.org/10.1016/S0960-894X(00)00422-4] [PMID: 10999482]
[9]
Heindel, N.D.; Reid, J.R. J. Heterocycl. Chem., 1980, 17, 1087-1088.
[http://dx.doi.org/10.1002/jhet.5570170547]
[10]
Glennon, R.A.; Seggel, M.R.; Soine, W.H.; Herrick-Davis, K.; Lyon, R.A.; Titeler, M. J. Med. Chem., 1988, 31(1), 5-7.
[http://dx.doi.org/10.1021/jm00396a003] [PMID: 3336031]
[11]
Stankovsky, S.; Jedlovska, F.; Spirkova, K. Collect. Czech. Chem. Commun., 1993, 58, 2211-2214.
[http://dx.doi.org/10.1135/cccc19932211]
[12]
Krimer, M.Z.; Tashch, V.P.; Kalyan, Y.B.; Bakaev, F.Z.; Putskin, Y.G.; Molchanov, O.Y. Pharm. Chem. J., 1995, 29, 764-769.
[http://dx.doi.org/10.1007/BF02331857]
[13]
Sudha, R.K.; Kandula, P.; Anupama, B.; Lakshmi, K.N. International Journal of Pharmacy &. Life Sci., 2015, 6, 4417-4426.
[14]
Ramesh, R.; Lalitha, A. ChemistrySelect, 2016, 1, 2085-2089.
[http://dx.doi.org/10.1002/slct.201600348]
[15]
Wujec, M.; Pitucha, M.; Dobosz, M.; Kosikowska, U.; Malm, A. Acta Pharm., 2004, 54(3), 251-260.
[PMID: 15610621]
[16]
Pitucha, M.; Wujec, M.; Dobosz, M. J. Chin. Chem. Soc. (Taipei), 2007, 54, 69-73.
[http://dx.doi.org/10.1002/jccs.200700012]
[17]
Zamani, K.; Faghihi, K.; Tofighi, T.; Shariatzadeh, M.R. Turk. J. Chem., 2004, 28, 95-100.
[18]
Guda, D.R.; Wang, T.; Cho, H.M.; Lee, M.E. Tetrahedron Lett., 2012, 53, 5238-5242.
[http://dx.doi.org/10.1016/j.tetlet.2012.07.054]
[19]
Farghaly, A.R.; El-Kashef, H. ARKIVOC, 2006, 11, 79-90.
[20]
Guelerman, N.; Rollas, S.; Uelgen, M. Boll. Chim. Farm., 1998, 137, 140-143.
[PMID: 9689899]
[21]
Salgin-Gökşen, U.; Gökhan-Kelekçi, N.; Göktaş, O.; Köysal, Y.; Kiliç, E.; Işik, S.; Aktay, G.; Özalp, M. Bioorg. Med. Chem., 2007, 15(17), 5738-5751.
[http://dx.doi.org/10.1016/j.bmc.2007.06.006] [PMID: 17587585]
[22]
Patil, J.D.; Pore, D.M. RSC Advances, 2014, 4, 14314-14319.
[http://dx.doi.org/10.1039/c3ra46916f]
[23]
Pore, D.M.; Hegade, P.G.; Mane, M.M.; Patil, J.D. RSC Advances, 2013, 3, 25723-25726.
[http://dx.doi.org/10.1039/c3ra44641g]
[24]
Patil, P.B.; Patil, J.D.; Korade, S.N.; Kshirsagar, S.D.; Govindwar, S.P.; Pore, D.M. Res. Chem. Intermed., 2016, 42, 4171-4180.
[http://dx.doi.org/10.1007/s11164-015-2267-z]
[25]
Mane, M.M.; Pore, D.M. Tetrahedron Lett., 2014, 55, 6601-6604.
[http://dx.doi.org/10.1016/j.tetlet.2014.10.052]
[26]
Mali, D.A.; Telvekar, V.N. Syn. Comm., 2017, 47, 324-329.
[http://dx.doi.org/10.1080/00397911.2016.1263338]
[27]
Maddila, S.N.; Maddila, S.; Gangu, K.K.; Van Zyl, W.E.; Jonnalagadda, S.B. J. Fluor. Chem., 2017, 195, 79-84.
[http://dx.doi.org/10.1016/j.jfluchem.2017.01.012]

Rights & Permissions Print Cite
© 2024 Bentham Science Publishers | Privacy Policy