Vanadium Oxide Nanofibers: Synthesis and Research on Functional Properties

Author(s): O. Ya. Berezina, N.P. Markova, E.N. Kolobova, A.L. Pergament*, D.S. Yakovleva, V.P. Zlomanov, N.V. Krivoshchapov

Journal Name: Micro and Nanosystems

Volume 12 , Issue 1 , 2020

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Graphical Abstract:


Aim: Vanadium oxide nanofibers have been manufactured by the sol–gel electrospinning method followed by the thermal treatment in air and argon.

Materials and Methods: The samples are characterized by optical, laser confocal and scanning electron microscopy, energy-dispersive X-ray elemental analysis, X-ray diffraction, cyclic voltammetry, and electrical conductivity measurements.

Results: The obtained VO2 nanofibers demonstrate the semiconductor-to-metal phase transition. Also, the vanadium pentoxide nanofibers are examined as electrode materials for rechargeable Li-ion batteries.

Keywords: Vanadium oxides, sol-gel, nanofibers, semiconductor-metal phase transition, Li-ion batteries, treatment, scanning electron, microscopy.

Vadnala, S.; Paul, N.; Agrawal, A.; Singh, S.G. Enhanced infrared sensing properties of vanadium pentoxide nanofibers for bolometer application. Mater. Sci. Semicond. Process., 2018, 81, 82-88.
Liu, K.; Lee, S.; Yang, S.; Delaire, O.; Wu, J. Recent progresses on physics and applications of vanadium dioxide. Mater. Today, 2018, 21, 875-896.
Velichko, A.; Pergament, A.; Putrolaynen, V.; Berezina, O.; Stefanovich, G. Effect of memory electrical switching in metal/vanadium oxide/silicon structures with VO2 films obtained by the sol–gel method. Mater. Sci. Semicond. Process., 2015, 29, 315-320.
Wruck, D.; Ramamurthi, S.; Rubin, M. Sputtered electrochromic V2O5 films. Thin Solid Films, 1989, 182, 79-86.
Burdyukh, S.V.; Berezina, O.Y.; Pergament, A.L.; Lugovskaya, L.A.; Kolyagin, Yu.G. Effect of hydrogenation on the optical properties and internal electrochromism in vanadium pentoxide xerogel films. Thin Solid Films, 2018, 656, 22-29.
Yan, B.; Li, X.; Bai, Z.; Li, M.; Dong, L.; Xiong, D.; Li, D. Superior lithium storage performance of hierarchical porous vanadium pentoxide nanofibers for lithium ion battery cathodes. J. Alloys Compd., 2015, 634, 50-57.
Berezina, O.; Kirienko, D.; Pergament, A.; Stefanovich, G.; Velichko, A.; Zlomanov, V. Vanadium oxide thin films and fibers obtained by acetylacetonate sol-gel method. Thin Solid Films, 2015, 574, 15-19.
Berezina, O.Y.; Kirienko, D.A.; Markova, N.P.; Pergament, A.L. Synthesis of vanadium pentoxide micro- and nanofibers by electrospinning. Tech. Phys., 2015, 60, 1361-1366.
Berenguer, R.; Guerrero-Pérez, M.O.; Guzmán, I.; Rodríguez-Mirasol, J.; Cordero, T. Synthesis of vanadium oxide nanofibers with variable crystallinity and V5+/V4+ ratios. ACS Omega, 2017, 2, 7739-7745.
Nishide, H.; Oyaizu, K. Materials science. Toward flexible batteries. Science, 2008, 319(5864), 737-738.
[] [PMID: 18258887]
Afyon, S.; Krumeich, F.; Mensing, C.; Borgschulte, A.; Nesper, R. New high capacity cathode materials for rechargeable Li-ion batteries: Vanadate-borate glasses. Sci. Rep.,, 2014, 4, 7113-1-7113-7.
Xue, Y.; Castracane, J.; Gadre, A.; Lee, J.H.; Altemus, B. Fabrication and characterization of aligned continuous polymeric electrospun nanofibers. Micro Nanosyst., 2009, 1, 116-122.
Alonco, B.; Livage, J. Synthesis of vanadium oxide gels from peroxovanadic acid solutions: A 51 V NMR study. J. Solid State Chem., 1999, 148, 16-19.
Leroux, Ch.; Nihoul, G.; Van Tendeloo, G. From VO2(B) to VO2(R): Theoretical structures of VO2 polymorphs and in situ electron microscopy. Phys. Rev. B Condens. Matter Mater. Phys., 1998, 57, 5111-5121.
Su, H.; Chang, K.; Ma, Y.; Yang, D.; Wang, C.; Zhang, K.; Li, D.; Zhang, J. Hierarchical flower-like structures composed of cross-shaped vanadium dioxide nanobelts as superior performance anode for lithium and sodium ions batteries. Appl. Surf. Sci., 2019, 480, 882-887.

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Article Details

Year: 2020
Published on: 05 August, 2019
Page: [68 - 74]
Pages: 7
DOI: 10.2174/1876402911666190806104117

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