Vegetable Oils in the Production of Biodegradable Alkyd Resins

Author(s): Marcin Bartkowiak*, Eugeniusz Milchert, Łukasz Sałaciński

Journal Name: Mini-Reviews in Organic Chemistry

Volume 16 , Issue 4 , 2019

Become EABM
Become Reviewer

Graphical Abstract:


Abstract:

A review of the technological principles of the production of alkyd resins modified with vegetable oils has been presented. Reactions and transformations occurring during the crosslinking in the presence of unsaturated fatty acids and mono-, di- and triglycerides have been described. Influence of the addition of other resins to modified glyptals and pentaphthalates have been presented. Research trends indicate the growing importance of nanomaterials in the preparation of alkyd coatings with improved properties.

Keywords: Alkyd resins, coatings, glyptal resins, nanocomposites, pentaphthalates, vegetable oils.

[1]
Kłos, M.; Milchert, E.; Malarczyk, K. Industrial uses of vegetable oils. Przem. Chem., 2016, 95, 1000-1006.
[2]
Hofland, A. Alkyd resins: From down and out to alive and kicking. Prog. Org. Coat., 2012, 73, 274-282.
[3]
Haseebuddin, S.; Parmar, R.; Waghoo, G.; Glosh, S.K. Study of hexafunctional polyols in high solids air-drying alkyd: Improved film performance. Prog. Org. Coat., 2009, 64, 446-453.
[4]
Alam, M.; Akram, D.; Sharmin, E.; Zafar, F.; Ahmad, S. Vegetable oil based eco-friendly coating materials: A review article. Arabian . J. Chem., 2014, 7, 469-479.
[5]
Muizebelt, W.J.; Hubert, J.C.; Nielen, M.W.F.; Klaasen, R.P.; Zabel, K.H. Crosslink mechanisms of high-solids alkyd resins in the presence of reactive diluents. Prog. Org. Coat., 2000, 40, 121-130.
[6]
Szlezyngier, W.; Brzozowski, Z. Plastics.Vol. 1:; Wydawnictwo Oświatowe Fosze: Rzeszów, Poland, 2012.
[7]
Akintayo, C.O.; Adebowale, K.O. Synthesis and characterization of acrylated Albizia benth medium oil alkyds. Prog. Org. Coat., 2004, 50, 207-212.
[8]
Dutta, N.; Karak, N.; Dolui, S.K. Alkyd-epoxy blends as multipurpose coatings. J. Appl. Polym. Sci., 2006, 100, 516-521.
[9]
Heiskanen, N.; Jamsa, S.; Paajanen, L.; Koskimies, S. Synthesis and performance of alkyd acrylic hybryd binders. Prog. Org. Coat., 2010, 67, 329-338.
[10]
Aigbodion, A.I.; Okiemen, F.E.; Iukhuoria, E.U.; Bakare, I.O.; Obazee, E.O. Rubber seed oil modified with maleic anhydride and fumaric acid and their alkyd resins as binders inwater-reducible coatings. J. Appl. Polym. Sci., 2003, 89, 3286-3259.
[11]
Saravari, O.; Phapant, P.; Pimpan, V. Synhesis of water-reducible acrylic-alkyd resins based on modified palm oil. J. Appl. Polym. Sci., 2005, 96, 1170-1175.
[12]
Althawale, V.D.; Nimbalkar, R.V. Emulsifyable air drying urethane. Prog. Org. Coat., 2010, 67, 66-71.
[13]
Dhoke, S.K.; Khanna, A.S.; Sinha, T.K.M. Effect of nano-ZnO particles on the corrosion behavior of alkyd based waterborne coatings. Prog. Org. Coat., 2009, 64, 371-382.
[14]
Dhoke, S.K.; Khanna, A.S. Effect of nano-ZnO addition on the silicone-modified alkyd-based waterborne coatings on its mechanical and heat-resistance properties. Prog. Org. Coat., 2009, 64, 39-46.
[15]
Dhoke, S.K.; Bhandari, R.; Khanna, A.S. Effect of nano-Fe2O3 particles on the corrosion behavior of alkyd based waterborne coatings. Corr. Sci., 2009, 51, 6-20.
[16]
Alam, J.; Riaz, U.; Ahmad, S. High performance corrosion resistant polyaniline/alkyd ecofriendly coatings. Curr. Appl. Phys., 2009, 9, 80-86.
[17]
Alam, J.; Riaz, U.; Ashraf, S.M.; Ahmad, S. Corrosion-protective performance of nano polyaniline/ferrite dispersed alkyd coatings. J. Coat. Technol. Res., 2008, 5(1), 123-128.
[18]
Sailer, R.A.; Wegner, J.R.; Hurtt, G.J.; Janson, J.E.; Soucek, M.D. Linseed and sunflower oil alkyd creamers. Prog. Org. Coat., 1998, 33, 117-125.
[19]
Saravari, O.; Praditvatanakit, S. Preparation and properties of urethane alkyd based on a castor oil/jatropha oil mixture. Prog. Org. Coat., 2013, 76, 698-704.
[20]
Pathan, S.; Ahmad, S. Synthesis, characterization and effect of s-triazine ring on physico-mechanical and electrochemical corrosion resistance performance of waterborne castor oil alkyd. J. Mater. Chem. A., 2013, 1, 14227-14238.
[21]
Pathan, S.; Ahmad, S. S-triazine ring modified waterborne alkyd: Synthesis, characterization, antibacterial and electrochemical corrosion studies. ACS Sustain. Chem., 2013, 1, 1246-1257.
[22]
Sałaciński, Ł.; Milchert, E. Epoxidized vegetable oils in the production of coatings. Przem. Chem., 2017, 96(5), 1000-1005.
[23]
Milchert, E.; Malarczyk, K.; Kłos, M. Technological aspects of chemoenzymatic epoxidation of fatty acids, fatty acid esters and vegetable oils: A review. Molecules, 2015, 20, 21481-21493.
[24]
Huang, K.; Zhang, P.; Zhang, J.; Li, S.; Li, M.; Xia, J.; Zhou, Y. Preparation of biobased epoxies using tung oil fatty acid-derived C21 diacid and C22 triacid and study of epoxy properties. Green Chem., 2013, 15, 1466-1472.
[25]
Narine, S.S.; Yue, J.; Kong, X. Production of polyols from canola oil and their chemical identyfication and physical properties. J. Amer. Oil Chem. Soc., 2007, 84, 173-179.
[26]
Desroches, M.; Escouvois, M.; Auvergne, R.; Caillol, S.; Boutevin, B. From vegetable oils to polyurethanes: Synthetic routes to polyols and main industrial products. Polym. Rev., 2012, 52(1), 38-79.
[27]
Meshram, P.D.; Puri, R.G.; Patil, A.L.; Gite, V.V. Synthesis and chacterization of modified cottonseed oil based polyesteramide for coating applications. Prog. Org. Coat., 2013, 76, 1144-1150.
[28]
Zafar, F.; Sharmin, E.; Ashraf, S.M.; Ahmad, S. Ambient cured polyesteramide-based anticorrosive coatings from linseed oil a sustainable resource. J. Appl. Polym. Sci., 2008, 97, 1818-1824.


Rights & PermissionsPrintExport Cite as

Article Details

VOLUME: 16
ISSUE: 4
Year: 2019
Page: [399 - 404]
Pages: 6
DOI: 10.2174/1570193X15666181001130019
Price: $65

Article Metrics

PDF: 39
HTML: 1