Copper-catalyzed N-Arylation of the Adduct of Malononitrile and Trichloroacetonitrile

Author(s): Manijeh Nematpour*, Elham Abedi, Elahe Abedi, Mahbob Lotfi

Journal Name: Letters in Organic Chemistry

Volume 15 , Issue 9 , 2018


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Graphical Abstract:


Abstract:

The synthesis of a novel class of trichloro-1-{(N-arylamino)ethylidene}malononitrile via a copper-catalyzed multicomponent reaction of malononitrile-trichloroacetonitrile adduct and aryl halides in good yields is described. The reported protocol has some advantages such as simple and mild procedure, easy work-up, no column chromatography, available starting materials-catalyst, pure products and good to high yields.

Keywords: N-Arylation, ullmann coupling, trichloroacetonitrile, copper-catalyzed, trichloro-1-{(N-arylamino)ethylidene} malononitrile, malononitrile.

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Article Details

VOLUME: 15
ISSUE: 9
Year: 2018
Published on: 26 July, 2018
Page: [727 - 730]
Pages: 4
DOI: 10.2174/1570178614666170810125505
Price: $65

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