Molecular Complexes of Monoammonium Glycyrrhizinate with Alphahederin and Hederasaponin C

Author(s): Leonid A. Yakovishin, Vladimir I. Grishkovets, Elena N. Korzh

Journal Name: Letters in Organic Chemistry

Volume 12 , Issue 2 , 2015

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Abstract:

Molecular complexes of monoammonium glycyrrhizinate (glycyram) with triterpene glycosides from ivy alpha- hederin (hederagenin 3-O-α-L-rhamnopyranosyl-(1→2)2)-O-α-L-arabinopyranoside) and hederasaponin C (hederagenin 3-O-α-L-rhamnopyranosyl-(1→2)-O-α-L-arabinopyranosyl-28-0-α-L-rhamnopyranosyl-(1→4)-0-β-D-glucopyranosyl-( 1→6)-0-β-D-glucopyranoside) have been prepared for the first time. The complexation has been investigated by FT-IR and UV spectroscopy. The glycosides form complexes in the 1:1 molar ratio. The allelopathic activity and ichthyotoxicity of the molecular complexes have been considered.

Keywords: Alpha-hederin, hederasaponin C, monoammonium glycyrrhizinate, molecular complex.

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Article Details

VOLUME: 12
ISSUE: 2
Year: 2015
Page: [109 - 114]
Pages: 6
DOI: 10.2174/1570178612666141230234729
Price: $65

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