Abstract
The design and synthesis of molecular container compounds is playing an important role in host–guest chemistry. Porous organic molecular cages (OMCs) represent an exciting type of container-like compounds and have attracted intensive attention in the past few decades. These materials are constructed through covalent bonds and can be synthesized in reasonable yield by making use of dynamic covalent chemistry. Furthermore, they can pack to form crystalline materials with void spaces, thus showing potential applications in gas absorption and molecular separation. In this article, we highlight the state-of-the-art development in the synthesis, functionalization and application of OMCs.
Keywords: Dynamic covalent chemistry, gas absorption and separation, molecular container compounds, molecular reaction flask, molecular recognition, porous solid materials.
Current Organic Chemistry
Title:Porous Organic Molecular Cages: from Preparation to Applications
Volume: 18 Issue: 15
Author(s): Ming Xiong, Huimin Ding, Bijian Li, Tailin Zhou and Cheng Wang
Affiliation:
Keywords: Dynamic covalent chemistry, gas absorption and separation, molecular container compounds, molecular reaction flask, molecular recognition, porous solid materials.
Abstract: The design and synthesis of molecular container compounds is playing an important role in host–guest chemistry. Porous organic molecular cages (OMCs) represent an exciting type of container-like compounds and have attracted intensive attention in the past few decades. These materials are constructed through covalent bonds and can be synthesized in reasonable yield by making use of dynamic covalent chemistry. Furthermore, they can pack to form crystalline materials with void spaces, thus showing potential applications in gas absorption and molecular separation. In this article, we highlight the state-of-the-art development in the synthesis, functionalization and application of OMCs.
Export Options
About this article
Cite this article as:
Xiong Ming, Ding Huimin, Li Bijian, Zhou Tailin and Wang Cheng, Porous Organic Molecular Cages: from Preparation to Applications, Current Organic Chemistry 2014; 18 (15) . https://dx.doi.org/10.2174/1385272819666140514004934
DOI https://dx.doi.org/10.2174/1385272819666140514004934 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
Call for Papers in Thematic Issues
Advances of Heterocyclic Chemistry with Pesticide Activity
Global food safety and security will continue to be a global concern for the next 50 years and beyond. Plant diseases have had a significant impact on food safety and security throughout the entire food chain, from primary production to consumption. While conventional chemical pesticides have been traditionally used for ...read more
Calculation design of covalent/metal organic framework based catalysts
This research area combines theoretical computation and screening with machine learning for the design of covalent/metal organic framework-based catalysts, bridging the disciplines of organic chemistry, physical chemistry, computational chemistry, materials science, and machine learning. It covers several critical aspects: designing and synthesizing organic catalysts for improved performance, applying computational methods ...read more
Carbohydrates conversion in biofuels and bioproducts
Biomass pretreatment, hydrolysis, and saccharification of carbohydrates, and sugars bioconversion in biofuels and bioproducts within a biorefinery framework. Carbohydrates derived from woody biomass, agricultural wastes, algae, sewage sludge, or any other lignocellulosic feedstock are included in this issue. Simulation, techno-economic analysis, and life cycle analysis of a biorefinery process are ...read more
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
Related Journals
- Author Guidelines
- Graphical Abstracts
- Fabricating and Stating False Information
- Research Misconduct
- Post Publication Discussions and Corrections
- Publishing Ethics and Rectitude
- Increase Visibility of Your Article
- Archiving Policies
- Peer Review Workflow
- Order Your Article Before Print
- Promote Your Article
- Manuscript Transfer Facility
- Editorial Policies
- Allegations from Whistleblowers
- Announcements