A New Synthesis for Acacetin, Chrysoeriol, Diosmetin, Tricin and Other Hydroxylated Flavones by Modified Baker-Venkataraman Transformation

Author(s): N. Pandurangan

Journal Name: Letters in Organic Chemistry

Volume 11 , Issue 3 , 2014

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Abstract:

Baker-Venkataraman (BV) rearrangement is the method of choice for the synthesis of flavones. The major limitation of BV is that it requires extensive protections and deprotections of hydroxyl groups which make the process lengthy and cumbersome. In the present study, a three step efficient method has been developed using simple protecting groups and easily available starting materials. New syntheses for acacetin, chrysoeriol, diosmetin, tricin and other hydroxylated flavones are described.

Keywords: Baker-Venkataraman transformation, partial methyl ethers, polyhydroxyflavones.

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Article Details

VOLUME: 11
ISSUE: 3
Year: 2014
Published on: 06 February, 2014
Page: [225 - 229]
Pages: 5
DOI: 10.2174/1570178611999140206115633
Price: $65

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