Alkylboronate Synthesis Based on Transition Metal-Catalyzed Hydroboration.

Author(s): Saipeng Huang, Yuanchao Xie, Shaolei Wu, Meirong Jia, Junhua Wang, Wenfeng Xu, Hao Fang

Journal Name: Current Organic Synthesis

Volume 10 , Issue 5 , 2013

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Alkylboronate derivatives are important intermediates in organic synthesis and medicinal chemistry. The research of synthesizing alkylboronic acid derivatives has attracted great attention of chemists and many papers have reported various methods for preparing alkylboronates based on transition-metal-catalyzed hydroboration. In this review, we summarize the methods of synthesizing alkylboronate derivatives with different catalysts, such as Rhodium, Palladium, Copper, Iridium, Iron, Magnesiu, Platinum, Nickel and so on. Pinacolborane, bispinacolatodiboron and catecholborane are applied as important reagents and substrates with different skeleton structures and functional groups are employed to prepare diversity of alkylboronates.

Keywords: Alkylboronate, alkylboronic derivatives, catalyst, hydroboration, transition metal.

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Article Details

Year: 2013
Published on: 09 October, 2013
Page: [683 - 696]
Pages: 14
DOI: 10.2174/15701794113109990060
Price: $65

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