Abstract
Acyclic diene metathesis polymerization (ADMET) has taken a long path from its beginnings with Schrock catalyst and unfunctionalized dienes to use of Grubbs catalysts with nearly unlimited choices for pendant groups and chain composition. This review covers synthesis of model linear polyethylene via ADMET polymerization, synthesis of polymers from green feed stocks, and the effect of spacer length on morphology and polymer properties. By taking advantage of ADMET’s functional group tolerance, it can be used in conjunction with a variety of other organic transformations and in-chain functional groups to yield unique architectures and properties. These topics will demonstrate the utility of ADMET in the future of polymer science.
Keywords: ADMET, metathesis, catalyst, renewable feed stocks, ionomers, conjugated materials, specialty polymers.
Call for Papers in Thematic Issues
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This research area combines theoretical computation and screening with machine learning for the design of covalent/metal organic framework-based catalysts, bridging the disciplines of organic chemistry, physical chemistry, computational chemistry, materials science, and machine learning. It covers several critical aspects: designing and synthesizing organic catalysts for improved performance, applying computational methods ...read more
Carbohydrates conversion in biofuels and bioproducts
Biomass pretreatment, hydrolysis, and saccharification of carbohydrates, and sugars bioconversion in biofuels and bioproducts within a biorefinery framework. Carbohydrates derived from woody biomass, agricultural wastes, algae, sewage sludge, or any other lignocellulosic feedstock are included in this issue. Simulation, techno-economic analysis, and life cycle analysis of a biorefinery process are ...read more
Catalytic C-H bond activation as a tool for functionalization of heterocycles
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