Synthesis of a Rigid Fused Porphyrin-Phthalocyanine Hetero-Dyad with Two Different Metals

Author(s): Mario J.F. Calvete, Joao P.C. Tome, Jose A.S. Cavaleiro

Journal Name: Current Organic Chemistry

Volume 17 , Issue 10 , 2013

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The synthesis and characterization of the first rigid fused porphyrin-phthalocyanine hetero-dyad with two different metals is reported; was based on porphyrin’s dienophile features in Diels–Alder reactions. This synthetic procedure represents a new approach for the synthesis of extended systems based on tetrapyrrolic macrocycles.

Keywords: Bimetallic systems, Diels-Alder reactions, Extended heterocyclic systems, Porphyrins, Phthalocyanines.

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Article Details

Year: 2013
Page: [1103 - 1107]
Pages: 5
DOI: 10.2174/1385272811317100010
Price: $58

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