Abstract
Miniemulsion is a promising technology to prepare capsules taking advantage of its droplet nucleation and absence of molecular net diffusion between droplets. The versatile shell materials of capsules can be obtained via a normal free radical polymerization, controlled/ living radical polymerization, anionic polymerization, polyaddition, polycondensation of organic and inorganic precursors or coordination polymerization in miniemulsion. This review will concentrate on the preparation of capsules in miniemulsion via different formation mechanisms, including phase separation of polymers, interfacial reactions, and Ouzo effect.
Keywords: Capsules, Miniemulsion, Interfacial reaction, Ouzo effect, Polymer phase separation, (Co)Monomer, Poly(divinylbenzene) (PDVB), Inverse Miniemulsion, Pickering-type emulsification, solvent displacement technique
Current Organic Chemistry
Title:A Versatile Technique to Fabricate Capsules: Miniemulsion
Volume: 17 Issue: 1
Author(s): Zhihai Cao and Ulrich Ziener
Affiliation:
Keywords: Capsules, Miniemulsion, Interfacial reaction, Ouzo effect, Polymer phase separation, (Co)Monomer, Poly(divinylbenzene) (PDVB), Inverse Miniemulsion, Pickering-type emulsification, solvent displacement technique
Abstract: Miniemulsion is a promising technology to prepare capsules taking advantage of its droplet nucleation and absence of molecular net diffusion between droplets. The versatile shell materials of capsules can be obtained via a normal free radical polymerization, controlled/ living radical polymerization, anionic polymerization, polyaddition, polycondensation of organic and inorganic precursors or coordination polymerization in miniemulsion. This review will concentrate on the preparation of capsules in miniemulsion via different formation mechanisms, including phase separation of polymers, interfacial reactions, and Ouzo effect.
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Cite this article as:
Cao Zhihai and Ziener Ulrich, A Versatile Technique to Fabricate Capsules: Miniemulsion, Current Organic Chemistry 2013; 17 (1) . https://dx.doi.org/10.2174/138527213805289169
DOI https://dx.doi.org/10.2174/138527213805289169 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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