Gold(III)-catalyzed Intermolecular Hydroamination of C-(tetra-O-acetyl- β -D-galactopyranosyl)allene

Author(s): Chaleowsak Khamwong, Senee Kruanetr, Uthai Sakee

Journal Name: Letters in Organic Chemistry

Volume 9 , Issue 9 , 2012

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The intermolecular hydroamination of C-(tetra-O-acetyl-β-D- galactopyranosyl)allene with a variety of aromatic amines proceeded smoothly in the presence of gold(III) catalyst to afford the corresponding allylic amine in good yields. The reaction can be carried out at room temperature and under extremely mild conditions.

Keywords: Allene, amine, galactopyranosyl, gold, hydroamination, intermolecular, allylic amine, Lewis acid, aromatic

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Article Details

Year: 2012
Page: [650 - 654]
Pages: 5
DOI: 10.2174/157017812803521162
Price: $65

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