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Mini-Reviews in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-193X
ISSN (Online): 1875-6298

Homogeneous CrVI-Catalyzed Benzylic, Allylic and Propargylic Oxidations by tert- Butyl Hydroperoxide

Author(s): J. Muzart

Volume 6, Issue 1, 2009

Page: [9 - 20] Pages: 12

DOI: 10.2174/157019309787316120

Price: $65

Abstract

Environmental factors urge to use catalytic rather than stoichiometric oxidation methods. Over the last thirty years, we have reported a large panel of Cr-catalyzed oxidations. This mini-review concerns the benzylic, allylic and propargylic oxidations using CrVI catalysts and t-BuOOH under homogeneous conditions, and summarizes our results and those of the literature.

Keywords: Chromium oxides, tert-butyl hydroperoxide, catalysis, benzylic oxidation, allylic oxidation, propargylic oxidation, mechanism


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