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Letters in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

Palladium or Iridium-Catalyzed Allylic Substitution of Guanidines having Electron-Withdrawing Substituents

Author(s): Hideto Miyabe, Akira Matsumura, Kazumasa Yoshida, Masashige Yamauchi and Yoshiji Takemoto

Volume 1, Issue 2, 2004

Page: [119 - 121] Pages: 3

DOI: 10.2174/1570178043488464

Price: $65

Abstract

As a new direct functionalization of guanidines, the N-allylic substitution of guanidines was studied. The nitrogen atom of guanidine derivatives having two Nelectron- withdrawing substituents acted as a reactive nucleophile in the allylic substitution.

Keywords: guanidine, palladium, iridium, catalytic reaction, allylation, allylic substitution


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