Abstract
β-cyclodextrin based Batch, Flow-Through and “Teabag” Prototype Molecular Reactors have been assembled and used in variety of conventional synthetically useful free radical transformations (Hydrogen Transfer Reactions, Radical Cascade Reactions and Mn(OAc)3 mediated cascade/oxidation reactions. Reactions proceeded smoothly in all cases in good to excellent yields at ambient temperature in aqueous and organic media. The advantages of newly assembled setup are ease of setup, recyclability of the β-cyclodextrin media, flexibility and scope of the transformations to be performed and ease of scale-up of methodology.
Keywords: free radical synthesis, molecular reactors, flow through chemistry, tea-bag methodology, streamlining, β-cyclodextrins, Radical chemistry, batch reactors, prototype flow-through, “teabag” molecular reactors
Current Nanoscience
Title: Towards Streamlining Conventional Radical Reactions Through Development of β-cyclodextrin based Batch, Flow-Through and “Teabag” Prototype Molecular Reactors
Volume: 7 Issue: 5
Author(s): Victoria Tamara Perchyonok
Affiliation:
Keywords: free radical synthesis, molecular reactors, flow through chemistry, tea-bag methodology, streamlining, β-cyclodextrins, Radical chemistry, batch reactors, prototype flow-through, “teabag” molecular reactors
Abstract: β-cyclodextrin based Batch, Flow-Through and “Teabag” Prototype Molecular Reactors have been assembled and used in variety of conventional synthetically useful free radical transformations (Hydrogen Transfer Reactions, Radical Cascade Reactions and Mn(OAc)3 mediated cascade/oxidation reactions. Reactions proceeded smoothly in all cases in good to excellent yields at ambient temperature in aqueous and organic media. The advantages of newly assembled setup are ease of setup, recyclability of the β-cyclodextrin media, flexibility and scope of the transformations to be performed and ease of scale-up of methodology.
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Cite this article as:
Tamara Perchyonok Victoria, Towards Streamlining Conventional Radical Reactions Through Development of β-cyclodextrin based Batch, Flow-Through and “Teabag” Prototype Molecular Reactors, Current Nanoscience 2011; 7 (5) . https://dx.doi.org/10.2174/157341311797483718
DOI https://dx.doi.org/10.2174/157341311797483718 |
Print ISSN 1573-4137 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6786 |
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