Abstract
Organocatalyzed reactions can often be advantageously performed in non-traditional reaction media. Use of ionic liquids, water or brine often leads to improved yields and selectivities of organocatalytic transformations. In terms of energy source, organocatalyzed reactions can be significantly accelerated by microwave irradiation, ultrasound or high pressure. Reactions without solvent and performed in ball mills are also reviewed.
Keywords: Organocatalysis, water, ionic liqiuds, microwave irradiation, ultrasound, ball mill, Aldol Reactions, Michael Additions, Mannich Reactions in Aqueous Media, chloroform, dichloromethane, THF, toluene, trifluoroethanol, TBDPS-protected serine, Miscellaneous Reactions
Current Organic Chemistry
Title: Organocatalytic Reactions Under Unusual Conditions
Volume: 15 Issue: 13
Author(s): Stefan Toma, Radovan Sebesta and Maria Meciarova
Affiliation:
Keywords: Organocatalysis, water, ionic liqiuds, microwave irradiation, ultrasound, ball mill, Aldol Reactions, Michael Additions, Mannich Reactions in Aqueous Media, chloroform, dichloromethane, THF, toluene, trifluoroethanol, TBDPS-protected serine, Miscellaneous Reactions
Abstract: Organocatalyzed reactions can often be advantageously performed in non-traditional reaction media. Use of ionic liquids, water or brine often leads to improved yields and selectivities of organocatalytic transformations. In terms of energy source, organocatalyzed reactions can be significantly accelerated by microwave irradiation, ultrasound or high pressure. Reactions without solvent and performed in ball mills are also reviewed.
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Cite this article as:
Toma Stefan, Sebesta Radovan and Meciarova Maria, Organocatalytic Reactions Under Unusual Conditions, Current Organic Chemistry 2011; 15 (13) . https://dx.doi.org/10.2174/138527211796150723
DOI https://dx.doi.org/10.2174/138527211796150723 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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