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Current Organic Chemistry

Editor-in-Chief

ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

Metal Mediated and Catalyzed Nucleophilic Additions to Cyclopropenes

Author(s): Joseph M. Fox and Ni Yan

Volume 9, Issue 7, 2005

Page: [719 - 732] Pages: 14

DOI: 10.2174/1385272053765006

Price: $65

Abstract

This review describes the literature of nucleophilic additions of organometallic and metal hydride reagents to cyclopropenes with a particular focus on the regiochemical and stereochemical aspects of the addition reactions.

Keywords: walsh model, cyclopropene chemistry, carbometallation, electrophiles, alkylzinc addition, grignard reagents, cyclopropylbutyrolactones, natural products synthesis, hydroboration

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